This review summarizes the advances produced in the last 5 years in the use of mixed
ligands containing at least one phosphino and one pyridyl or related group (bipyridyl …

This review describes the main synthetic methodologies available for the preparation of P-
stereogenic phosphines and derivatives. The literature coverage focuses in the last ten …

Since the design of chiral ligands plays a key role in the development of metal-catalysed
asymmetric reactions, many recent studies have addressed the development of novel chiral …

This review describes some recent developments in the area of asymmetric catalysis using
organometallic complexes of ligands which contain two or three P–O or P–N bonds. This …

A Practical Method for the Large-Scale Synthesis of Diastereomerically Pure (2R,5S)- 3-Phenyl-2-(8-quinolinoxy)-
1,3-diaza-2-phosphabicyclo-[3.3.0]-octane Ligand (QUIPHOS). Synthesis and X-ray …

A new class of chiral amidine-phosphine hybrid ligands 7a, b, which are readily accessible
from the corresponding α-amino acids, were developed. A versatility for construction of new …

Ten types of new P-chiral phosphorodiamidite ligands having pyrrolo [1, 2-c][1, 3, 2]
diazaphosphol-1-one backbone were designed and prepared. They were preliminarily …

In recent years, Pd-catalyzed cross-coupling reactions have been used widely as
expeditious reactions in various fields of chemistry. Traditionally, these cross-coupling …

A gas pressure of only 8 bar is required for the effective asymmetric hydroformylation of vinyl
acetate with a new class of rhodium (i) catalysts. Key to successful catalysis is the chiral bis …

A series of chiral NCN pincer Pd (II) complexes with 1, 3-bis (2′-imidazolinyl) phenyl
(Phebim) ligands were synthesized via the C–H activation or oxidative addition method. A …