Defining the macromolecules of tomorrow through synergistic sustainable polymer research

FM Haque, JSA Ishibashi, CAL Lidston, H Shao… - Chemical …, 2022 - ACS Publications
Transforming how plastics are made, unmade, and remade through innovative research and
diverse partnerships that together foster environmental stewardship is critically important to …

Selective decarbonylation via transition-metal-catalyzed carbon–carbon bond cleavage

H Lu, TY Yu, PF Xu, H Wei - Chemical Reviews, 2020 - ACS Publications
Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

Palladium‐Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides

ST Keaveney, F Schoenebeck - Angewandte Chemie, 2018 - Wiley Online Library
While acid fluorides can readily be made from widely available or biomass‐feedstock‐
derived carboxylic acids, their use as functional groups in metal‐catalyzed cross‐coupling …

Transition-metal-free esterification of amides via selective N–C cleavage under mild conditions

G Li, P Lei, M Szostak - Organic letters, 2018 - ACS Publications
A general, transition-metal-free, and operationally simple method for esterification of amides
by a highly selective cleavage of N–C (O) bonds under exceedingly mild conditions is …

Transition-metal-catalyzed decarbonylation of carboxylic acids to olefins: exploiting acyl C–O activation for the production of high value products

X Zhang, F Jordan, M Szostak - Organic Chemistry Frontiers, 2018 - pubs.rsc.org
Transition-metal-catalyzed decarbonylation reactions of aliphatic carboxylic acids produce
olefins via one carbon degradation. Recently, tremendous progress has been made in the …

Selective production of linear α-olefins via catalytic deoxygenation of fatty acids and derivatives

A Chatterjee, SHH Eliasson, VR Jensen - Catalysis Science & …, 2018 - pubs.rsc.org
Scientists are exploring renewables as sources for a more sustainable production of
chemicals. Linear α-olefins (LAOs) are key commodity chemicals and petrochemical …

Copper-Catalyzed Decarboxylative Elimination of Carboxylic Acids to Styrenes

MP Stanton, JM Hoover - The Journal of Organic Chemistry, 2023 - ACS Publications
A copper-catalyzed decarboxylative elimination reaction of (hetero) aromatic propionic acids
to vinyl (hetero) arenes has been developed. This method furnishes alkenes from carboxylic …

Heterogeneous Non‐noble Catalyst for Highly Selective Production of Linear α‐Olefins from Fatty Acids: A Discovery of NiFe/C

Z Zhang, W Lin, Y Li, F Okejiri, Y Lu, J Liu… - …, 2020 - Wiley Online Library
Catalytic deoxygenation of even‐numbered fatty acids into odd‐chain linear α‐olefins
(LAOs) has emerged as a complementary strategy to oligomerization of ethylene, which only …

Selective Decarbonylation of Fatty Acids over the PtCo3Nx@NC Catalyst to Produce Long-Chain Olefins

Z Zhang, C Chen, Z Zhang, B Li… - Industrial & Engineering …, 2024 - ACS Publications
The decarbonylation of fatty acids presents a promising method for synthesizing sustainable
long-chain olefins. However, the development of catalysts that combine satisfactory …

Decarbonylation of carboxylic acids over H-mordenite

Z Zhou, H Liu, Z Chen, W Zhu, Z Liu - ACS Catalysis, 2021 - ACS Publications
Decarbonylation of carboxylic acids is an effective reaction for alkene production but suffers
from the requirement of homogeneous transitional-metal-based catalyst, ligand, and …