Relationship between Graft Density and the Dilute Solution Structure of Bottlebrush Polymers: An Inter-Chemistry Comparison and Scaling Analysis

DF Sunday, AB Burns, TB Martin, AB Chang… - …, 2023 - ACS Publications
Bottlebrush polymers are an important class of materials which consist of side chains grafted
along a linear backbone. There has been a significant effort to understand structure …

Direct-ink-write cross-linkable bottlebrush block copolymers for on-the-fly control of structural color

S Jeon, YL Kamble, H Kang, J Shi… - Proceedings of the …, 2024 - National Acad Sciences
Additive manufacturing capable of controlling and dynamically modulating structures down
to the nanoscopic scale remains challenging. By marrying additive manufacturing with self …

Cyclic vs Linear Bottlebrush Polymers in Solution: Side-Chain Length Effect

G Chen, EE Dormidontova - Macromolecules, 2023 - ACS Publications
Bottlebrush polymers (BBPs) of different architecture are of considerable interest for a broad
range of applications, including nanomedicine, electronics, and self-healing materials …

Beyond Traditional Stimuli: Exploring Salt-Responsive Bottlebrush Polymers─ Trends, Applications, and Perspectives

S Basak, R Chatterjee, A Bandyopadhyay - ACS omega, 2024 - ACS Publications
Bottlebrush polymers represent an important class of high-density side-chain-grafted
polymers traditionally with high molecular weights, in which one or more polymeric side …

Decoupling poly (3-alkylthiophenes)'backbone and side-chain conformation by selective deuteration and neutron scattering

Z Cao, Z Li, S Zhang, L Galuska, T Li, C Do… - …, 2020 - ACS Publications
Although considerable progress has been made to optimize the optoelectronic properties of
conjugated polymers (CPs), the rational design of CPs with tailored physical properties for …

Concentration-Driven Self-Assembly of PS-b-PLA Bottlebrush Diblock Copolymers in Solution

BB Patel, T Pan, Y Chang, DJ Walsh, JJ Kwok… - ACS Polymers …, 2022 - ACS Publications
Bottlebrush polymers are a class of semiflexible, hierarchical macromolecules with unique
potential for shape-, architecture-, and composition-based structure–property design. It is …

Synthesis and micellization of bottlebrush poloxamers

JF Hassler, NJ Van Zee, AA Crabtree, FS Bates… - ACS macro …, 2022 - ACS Publications
Bottlebrush polymers are characterized by an expansive parameter space, including graft
length and spacing along the backbone, and these features impact various structural and …

Melt properties and string model description of glass formation in graft polymers of different side-chain lengths

X Xu, WS Xu - Macromolecules, 2022 - ACS Publications
Graft polymers have attracted growing interest due to their unique properties, but a
fundamental understanding of their glass formation remains to be established. We perform …

Glycopolymers Prepared by Alternating Ring-Opening Metathesis Polymerization Provide Access to Distinct, Multivalent Structures for the Probing of Biological Activity

LC Mendez, FO Boadi, M Kennedy… - ACS Bio & Med …, 2024 - ACS Publications
A myriad of biological processes are facilitated by ligand–receptor interactions. The low
affinities of these interactions are typically enhanced by multivalent engagements to promote …

Coarse-Grained, Implicit Side-Chain Model of Bottlebrush Polymer Melts

H Kang, T Pan, CE Sing - Macromolecules, 2024 - ACS Publications
The unique architecture of bottlebrush polymers gives rise to multiple molecular parameters
consisting of the bottlebrush backbone length (N bb), side chain length (N sc), and grafting …