We review here the methods by which a silyl group, incorporated into an organic structure,
has been used in organic synthesis to control stereochemistry, or has been an integral but …

The remarkable development in homogeneous enantioselective catalysis reflected by the
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …

Compounds of silicon with coordination number greater than four have been known since
the beginning of the 19th century, when Gay-Lussac1 and J. Davy2 first observed …

The pioneering work of Tamao and Kumada I and Fleming 2 has introduced synthetic
organic chemists to the concept of using a silicon group as a masked hydroxy group. This …

N, N-Dimethylformamide (DMF) is frequently used as a solvent because of its unique
physical properties that allow it to solubilize both organic and inorganic substances. It has …

Reserpine (1) is one of the lipid-soluble indole alkaloids sharing the yohimbine pentacyclic
skeleton. Pharmacological studies have revealed that reserpine is a central nervous system …

The Phenyldimethylsilyl Group as a Masked Form of the Hydroxy Groupt Page 1 J . CHEM.
SOC., CHEM. COMMUN., 1984 29 The Phenyldimethylsilyl Group as a Masked Form of the …

A phenyldimethylsilyl group attached to carbon can be converted into a hydroxy group 1→ 5,
with retention of configuration at the migrating carbon, by any of three main methods. The …

The chemistry of azadirachtin - Natural Product Reports (RSC Publishing) DOI:10.1039/NP9931000109
Royal Society of Chemistry ViewáPDFáVersion á DOI:á10.1039/NP9931000109 (Review …

(Diisopropoxymethylsilyl)methyl Grignard reagent: a new, practically useful nucleophilic
hydroxymethylating agent Page 1 2120 J. Org. Chem. 2120-2122 10"6 and 1.4 X 10-4 M. None …