[HTML][HTML] An evaluation of corrosion processes affecting copper-coated nuclear waste containers in a deep geological repository

DS Hall, M Behazin, WJ Binns, PG Keech - Progress in Materials Science, 2021 - Elsevier
Permanent disposal of high level nuclear waste in containers that employ steel as a
structural element and copper as a corrosion barrier material is a favoured design concept in …

[HTML][HTML] A review of passivity breakdown on metal surfaces: influence of chloride-and sulfide-ion concentrations, temperature, and pH

H Parangusan, J Bhadra, N Al-Thani - Emergent Materials, 2021 - Springer
Metals, including austenitic steels and alloys, have been extensively applied in industrial
and engineering applications. Passive films on metal surfaces are very important for …

Electrochemical investigation and ab initio computation of passive film properties on copper in anaerobic sulphide solutions

D Kong, A Xu, C Dong, F Mao, K Xiao, X Li… - Corrosion …, 2017 - Elsevier
Electrochemical measurements based on the point defect model and ab initio calculations
were employed to investigate the properties of passive films formed on copper in anaerobic …

Transferable, highly crystalline covellite membrane for multifunctional thermoelectric systems

M Choi, G Lee, YL Lee, H Lee, JH Yang, H Jang… - InfoMat, 2024 - Wiley Online Library
Emerging freestanding membrane technologies, especially using inorganic thermoelectric
materials, demonstrate the potential for advanced thermoelectric platforms. However, using …

[HTML][HTML] Corrosion of copper-coated steel high level nuclear waste containers under permanent disposal conditions

T Standish, J Chen, R Jacklin, P Jakupi… - Electrochimica …, 2016 - Elsevier
The corrosion of high level nuclear waste containers under permanent disposal conditions
can occur via a number of processes which change in importance as the environment within …

Long-term corrosion of copper in a dilute anaerobic sulfide solution

J Chen, Z Qin, DW Shoesmith - Electrochimica acta, 2011 - Elsevier
The mechanism of corrosion of oxygen-free copper has been studied in stagnant aqueous
sulfide solutions using corrosion potential and electrochemical impedance spectroscopy …

Passivity breakdown on copper: influence of chloride ion

F Mao, C Dong, S Sharifi-Asl, P Lu, DD Macdonald - Electrochimica Acta, 2014 - Elsevier
Passivity breakdown and pitting on pure copper, the assumed material for the outer
canisters for the isolation of high-level nuclear waste in Sweden and Finland, has been …

Progress in the understanding of the long-term corrosion behaviour of copper canisters

F King, C Lilja, M Vähänen - Journal of Nuclear Materials, 2013 - Elsevier
Copper has been proposed as a canister material for the disposal of spent nuclear fuel in a
deep geologic repository in a number of countries worldwide. Since it was first proposed for …

Non-uniform film growth and micro/macro-galvanic corrosion of copper in aqueous sulphide solutions containing chloride

J Chen, Z Qin, T Martino, DW Shoesmith - Corrosion Science, 2017 - Elsevier
The corrosion of copper in aqueous sulphide environments is rapid and can occur under
transport limited conditions. At sufficiently high sulphide flux, microgalvanic corrosion can be …

Corrosion behaviour of copper under biotic and abiotic conditions in anoxic ground water: Electrochemical study

E Huttunen-Saarivirta, P Rajala, L Carpén - Electrochimica Acta, 2016 - Elsevier
Finnish nuclear waste disposal program proposes to dispose spent nuclear fuel in tightly
sealed copper canisters in a geological repository; here, copper acts as a corrosion barrier …