The electrochemical oxidation of aqueous sulfur dioxide: A critical review of work with respect to the hybrid sulfur cycle

JA O'brien, JT Hinkley, SW Donne, SE Lindquist - Electrochimica Acta, 2010 - Elsevier
Literature regarding the mechanism of the electrochemical oxidation of aqueous sulfur
dioxide to sulfuric acid has been critically evaluated to provide a detailed understanding of …

Polymer electrolyte fuel cells: science, applications, and challenges

AA Franco - 2016 - books.google.com
This book focuses on the recent research progress on the fundamental understanding of the
materials degradation phenomena in PEFC, for automotive applications. On a …

The impact of air contaminants on PEMFC performance and durability

Y Nagahara, S Sugawara, K Shinohara - Journal of Power Sources, 2008 - Elsevier
The impact of air contaminants such as sulfur compounds (SO2, H2S) and nitrogen
compounds (NOx and NH3) was investigated using subscale fuel cells. The severity of the …

Impact of sulfur dioxide on the oxygen reduction reaction at Pt/Vulcan carbon electrocatalysts

Y Garsany, OA Baturina… - Journal of the …, 2007 - iopscience.iop.org
The poisoning of the oxygen-reduction reaction (ORR) by adsorbed sulfur-containing
species was quantified for platinum fuel-cell materials using rotating ring disk electrode …

Deactivation of Pt/VC proton exchange membrane fuel cell cathodes by SO2, H2S and COS

BD Gould, OA Baturina, KE Swider-Lyons - Journal of Power Sources, 2009 - Elsevier
Sulfur contaminants in air pose a threat to the successful operation of proton exchange
membrane fuel cells (PEMFCs) via poisoning of the Pt-based cathodes. The deactivation …

Structure of chemisorbed sulfur on a Pt (111) electrode

YE Sung, W Chrzanowski, A Zolfaghari… - Journal of the …, 1997 - ACS Publications
Electron spectroscopic and diffraction results obtained in ultra-high-vacuum, combined with
cyclic voltammetric data, are reported for sulfur adlayers deposited from aqueous sulfide and …

Study of degradation and spatial performance of low Pt-loaded proton exchange membrane fuel cells under exposure to sulfur dioxide in an oxidant stream

T Reshetenko, V Laue, U Krewer… - Journal of Power Sources, 2020 - Elsevier
Sulfur dioxide is a common air pollutant that has an adverse impact on proton exchange
membrane fuel cells (PEMFCs). The present study reports the spatial performance and …

Deactivated Pt electrocatalysts for the oxygen reduction reaction: the regeneration mechanism and a regenerative protocol

YX Liu, WY Zhang, GK Han, YW Zhou, LF Li… - Acs …, 2021 - ACS Publications
Ambient contaminants, eg, sulfur dioxide (SO2), lead to severe Pt deactivation and
performance loss of practical proton exchange membrane (PEM) fuel cells, which need to be …

Potential dependence of sulfur dioxide poisoning and oxidation at the cathode of proton exchange membrane fuel cells

J Fu, M Hou, C Du, Z Shao, B Yi - Journal of Power Sources, 2009 - Elsevier
Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were employed
to investigate changes in the cathode after the introduction of SO2. The decay in …

Catalyst evaluation for a sulfur dioxide-depolarized electrolyzer

HR Colón-Mercado, DT Hobbs - Electrochemistry communications, 2007 - Elsevier
Thermochemical processes are being developed to provide global-scale quantities of
hydrogen. A variant on sulfur-based thermochemical cycles is the hybrid sulfur (HyS) …