Transition-metal-free coupling reactions

CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Catalytic dehydrogenative cross-coupling: forming carbon− carbon bonds by oxidizing two carbon− hydrogen bonds

CS Yeung, VM Dong - Chemical reviews, 2011 - ACS Publications
Inspired by the need for green and sustainable chemistry,(1) synthetic chemists seek more
efficient ways to construct carbon− carbon (C− C) bonds, the essential link in all organic …

Architecture of Supramolecular Metal Complexes for Photocatalytic CO2 Reduction:  Ruthenium−Rhenium Bi- and Tetranuclear Complexes

B Gholamkhass, H Mametsuka, K Koike… - Inorganic …, 2005 - ACS Publications
We study the electrochemical, spectroscopic, and photocatalytic properties of a series of Ru
(II)− Re (I) binuclear complexes linked by bridging ligands 1, 3-bis (4 '-methyl-[2, 2 '] …

Direct C–F bond formation using photoredox catalysis

M Rueda-Becerril, O Mahe, M Drouin… - Journal of the …, 2014 - ACS Publications
We have developed the first example of a photoredox catalytic method for the formation of
carbon–fluorine (C–F) bonds. The mechanism has been studied using transient absorption …

Synthesis, Structure, Photophysical Properties, and Redox Behavior of Cyclometalated Complexes of Iridium (III) with Functionalized 2, 2 '-Bipyridines

F Neve, A Crispini, S Campagna, S Serroni - Inorganic Chemistry, 1999 - ACS Publications
The new functionalized polypyridine ligands 4 '-(4-chlorophenyl)-6 '-phenyl-2, 2 '-bipyridine
(clpbpy), 4 '-(4-tolyl)-6 '-phenyl-2, 2 '-bipyridine (tpbpy), and 4 '-(4-carboxyphenyl)-6 '-phenyl …

Ruthenium (II) charge-Transfer sensitizers containing 4, 4 '-dicarboxy-2, 2 '-bipyridine. Synthesis, properties, and bonding mode of coordinated thio-and …

O Kohle, S Ruile, M Grätzel - Inorganic Chemistry, 1996 - ACS Publications
The synthesis and properties of several complexes of Ru (II) containing 4, 4 '-dicarboxy-2, 2 '-
bipyridine (dcbpyH2), 2, 6-bis (1-methylbenzimidazol-2-yl) pyridine (bmipy), or 2, 6-bis (1 …

Excited state processes in ruthenium (II)/pyrenyl complexes displaying extended lifetimes

DS Tyson, KB Henbest, J Bialecki… - The Journal of Physical …, 2001 - ACS Publications
The synthesis and photophysical properties of two Ru (II) diimine complexes bearing one
(dyad) and three (tetrad) pyrenyl units, respectively, are presented. The pyrene …

d → f Energy Transfer in a Series of IrIII/EuIII Dyads: Energy-Transfer Mechanisms and White-Light Emission

D Sykes, IS Tidmarsh, A Barbieri… - Inorganic …, 2011 - ACS Publications
An extensive series of blue-luminescent iridium (III) complexes has been prepared
containing two phenylpyridine-type ligands and one ligand containing two pyrazolylpyridine …

Energy transfer in rigid Ru (II)/Os (II) dinuclear complexes with biscyclometalating bridging ligands containing a variable number of phenylene units

F Barigelletti, L Flamigni, M Guardigli, A Juris… - Inorganic …, 1996 - ACS Publications
We have prepared rodlike cyclometalated Ru (II)/Os (II) dinuclear complexes,(ttp) Ru (dpb-
(ph) n-dpb) Os (ttp) 2+, where the biscyclometalating bridging ligands contain …

Synthesis of Unsymmetrically Substituted Bipyridines by Palladium-Catalyzed Direct C−H Arylation of Pyridine N-Oxides

S Duric, CC Tzschucke - Organic Letters, 2011 - ACS Publications
Substituted bipyridines were efficiently prepared by direct coupling between pyridine N-
oxides and halopyridines using a palladium catalyst. Pyridine N-oxides with electron …