Fundamentally-based kinetic model for propene pyrolysis
The primary objective of this work is to develop an improved fundamentally-based
mechanism that describes the molecular weight growth kinetics observed during propene …
mechanism that describes the molecular weight growth kinetics observed during propene …
Deoxy-Arylation of Amides via a Tandem Hydrosilylation/Radical–Radical Coupling Sequence
NJ Venditto, JA Boerth - Organic Letters, 2024 - ACS Publications
Vaska's complex is a prominent catalyst for the hydrosilylation of amides. The O-silyl
hemiaminal intermediate formed in these processes has been demonstrated as an …
hemiaminal intermediate formed in these processes has been demonstrated as an …
A comprehensive experimental and kinetic modeling study of 1-hexene
It is important to understand the low-temperature chemistry of 1-hexene as it is used as a
representative alkene component in gasoline surrogate fuels. Ignition delay times (IDTs) of 1 …
representative alkene component in gasoline surrogate fuels. Ignition delay times (IDTs) of 1 …
An experimental and kinetic modeling study of cyclopentane and dimethyl ether blends
Cyclopentane is a suitable naphthene, or cycloalkane, in a palette for multi-component
gasoline surrogate fuels due to its presence in market fuels and its relevance to alkyl …
gasoline surrogate fuels due to its presence in market fuels and its relevance to alkyl …
Autoignition of cyclohexane at low-to-intermediate temperatures: Rapid compression machine experiments and improved comprehensive chemical kinetic model
T Chatterjee, M Wang, SW Wagnon, G Kukkadapu… - Combustion and …, 2024 - Elsevier
Cycloalkanes are an important class of hydrocarbons found in conventional and alternative
transportation fuels. Being one of the simplest practical cycloalkanes, cyclohexane is often …
transportation fuels. Being one of the simplest practical cycloalkanes, cyclohexane is often …
Tacticity changes during controlled degradation of polypropylene
PD Iedema, K Remerie, D Seegers… - Macromolecules, 2021 - ACS Publications
The controlled reactive degradation of polypropylene (CPP) in a twin-screw extruder has
been investigated from the perspective of tacticity. CPP is initiated by the decomposition of a …
been investigated from the perspective of tacticity. CPP is initiated by the decomposition of a …
Experimental and kinetic modeling study of butene isomer pyrolysis: Part I. 1-and 2-Butene
and 2-Butene pyrolysis experiments were performed using a tubular flow reactor at an
absolute pressure of∼ 0.82 atm over a temperature range of 535–810° C with residence …
absolute pressure of∼ 0.82 atm over a temperature range of 535–810° C with residence …
A comprehensive experimental and kinetic modeling study of di-isobutylene isomers: Part 1
Di-isobutylene has received significant attention as a promising fuel blendstock, as it can be
synthesized via biological routes and is a short-listed molecule from the Co-Optima initiative …
synthesized via biological routes and is a short-listed molecule from the Co-Optima initiative …
Toward the development of a fundamentally based chemical model for cyclopentanone: High-pressure-limit rate constants for H atom abstraction and fuel radical …
Theoretical aspects of the development of a chemical kinetic model for the pyrolysis and
combustion of a cyclic ketone, cyclopentanone, are considered. Calculated thermodynamic …
combustion of a cyclic ketone, cyclopentanone, are considered. Calculated thermodynamic …
Experimental and kinetic modeling study of butene isomer pyrolysis: Part II. Isobutene
The pyrolysis of isobutene was investigated using a tubular flow reactor at an absolute
pressure of∼ 0.82 atm over a temperature range of 610–860° C with residence times …
pressure of∼ 0.82 atm over a temperature range of 610–860° C with residence times …