Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

K Bernot - European Journal of Inorganic Chemistry, 2023 - Wiley Online Library
The number of scientific articles that need to be considered to cover a research topic is ever‐
increasing and quite difficult for a newcomer to assimilate. This is particularly true in dynamic …

Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review

C Ebenezer, RV Solomon - Comments on Inorganic Chemistry, 2024 - Taylor & Francis
The development of density functional theory (DFT) has significantly enhanced the use of
computational chemistry as a tool in the design and development of ligands for the …

Synthesis, structure, and zero-field SMM behavior of homometallic Dy2, Dy4, and Dy6 complexes

P Kumar, A Swain, J Acharya, Y Li, V Kumar… - Inorganic …, 2022 - ACS Publications
The synthesis, structure, and magnetic properties of three DyIII complexes of different
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …

Boosting the mono-axial crystal field in stable high-coordinate Dy (III) single-ion magnets by substitution of the phenoxy axial ligand

B Zhang, Y Zhou, C Dong, Y Xiang, Y Shi… - Dalton …, 2023 - pubs.rsc.org
Synthesis of air-stable and high-performance single-molecule magnets (SMMs) is
challenging. Here, a heptadentate pentapyridyldiamine (BPA-TPA) ligand and fine-tuned …

Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets

J Wu, GL Wang, Z Zhu, C Zhao, XL Li… - Chemical …, 2022 - pubs.rsc.org
Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets -
Chemical Communications (RSC Publishing) DOI:10.1039/D2CC02570A Royal Society of …

A highly anisotropic family of hexagonal bipyramidal Dy (III) unsaturated 18-crown-6 complexes exceeding the blockade barrier over 2700 K: a computational …

S Moorthy, I Tarannum, K Kumari, SK Singh - Dalton Transactions, 2024 - pubs.rsc.org
In the present work, we have explored a series of unsaturated hexa-18-crown-6 (U18C6)
ligands towards designing highly anisotropic Dy (III) based single-ion magnets (SIMs) with …

Synthesis, Structure, and Magnetic Properties of Homometallic Mono-, Penta-, and Hexanuclear Dysprosium Complexes

WQ Li, QY Pan, QL Ni, SM Li, LC Gui… - Crystal Growth & …, 2023 - ACS Publications
Regulation of the complex structure is greatly significant for the preparation of single-
molecule magnets (SMMs). A Schiff base ligand, having suitably flexible coordination …

Dy4 and Dy5 complexes based on tautomeric hydrazone Schiff-base ligand regulated by temperature showing single-molecule magnet behaviour

X Zhong, ZB Hu, TK Luo, XF Chen, QY Zhang… - Journal of Molecular …, 2024 - Elsevier
Two dysprosium complexes [Dy 4 (H 2 L) 6]⋅ 4H 2 O (Dy 4) and [Dy 5 (H 2 L)(HL) 2 (L)(µ 3
single bond OH) 2 Cl (H 2 O)(MeCN) 2]⋅ 4MeOH⋅ 7H 2 O (Dy 5)(H 4 L=(N', N'''E, N', N'''E) …

[HTML][HTML] Engineering Mononuclear Ln(III) Complexes with a Pseudo-Macrocyclic Hexadentate N4O2 Schiff Base Ligand Exhibiting Slow Magnetic Relaxation

IF Diaz-Ortega, Y Ye, J Jover, E Ruiz, E Colacio… - Magnetochemistry, 2024 - mdpi.com
We report here the synthesis of a series of nine coordinated mononuclear LnIII complexes
[LnL1Cl2 (DMF)] Cl· 2.5 DMF and [LnL1 (L2) 2] Cl· 4CH3OH (LnIII= GdIII, DyIII, ErIII and YbIII …

Polar Lanthanide Anthracene Complexes Exhibiting Magnetic, Luminescent and Dielectric Properties

GB Sun, XD Huang, T Shang, S Yan… - European Journal of …, 2021 - Wiley Online Library
Multifunctional molecular materials combining magnetic, luminescent and dielectric
properties are attractive for potential applications in spintronics and molecular devices …