Criegee intermediates beyond ozonolysis: Synthetic and mechanistic insights

Z Hassan, M Stahlberger… - Angewandte Chemie …, 2021 - Wiley Online Library
After more than 70 years since their discovery, Criegee intermediates (CIs) are back at the
forefront of modern chemistry of short‐lived reactive intermediates. They play an important …

Carbonyl 1, 2-transposition through triflate-mediated α-amination

Z Wu, X Xu, J Wang, G Dong - Science, 2021 - science.org
To date, it remains challenging to selectively migrate a carbonyl oxygen within a given
molecular scaffold, especially to an adjacent carbon. In this work, we describe a simple one …

Synthesis of messagenin and platanic acid chalcone derivatives and their biological potential

E Khusnutdinova, Z Galimova, A Lobov… - Natural Product …, 2022 - Taylor & Francis
The chalcone derivatives of 20-oxo-lupanes have been synthesised and screened for some
types of biological activity. Ozonolysis of lupanes afforded 20-oxo-derivatives with the …

Synthesis of erythrodiol C-ring derivatives and their activity against Chlamydia trachomatis

O Kazakova, L Rubanik, A Lobov, N Poleshchuk… - Steroids, 2021 - Elsevier
To develop new potential agents against Chlamydia trachomatis among oleanane type
triterpenoids the synthesis, spectral and X-ray analysis as well as antimicrobial screening of …

24-Nor-allobetulins possess strong α-glucosidase inhibitory activity

L Zakirova, I Baikova, I Smirnova… - Natural Product …, 2023 - Taylor & Francis
A series of 24-nor-allobetulin derivatives holding 3β-hydroxy-, oxime, methoxyoxime,
lactame and 4-bromobenzylidene substituents have been synthesized and their differences …

Synthesis of 3-trifluoromethylated 1, 3-butadienes via a Pd (0)-catalyzed fluorinated Heck reaction

Y Li, M Hao, M Xia, N Sun, CL Zhang… - Reaction Chemistry & …, 2020 - pubs.rsc.org
1, 3-Butadienes play a key role in modern synthetic chemistry and biochemistry because
they are well-known precursors for the synthesis of retinoids. A new and efficient synthesis of …

New Amino-Derivatives of 24-Nor-Allobetulin

LM Zakirova, IP Baikova, YV Gatilov… - Chemistry of Natural …, 2024 - Springer
New Amino-Derivatives of 24-Nor-Allobetulin | Chemistry of Natural Compounds Skip to
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Uncommon Ozonolysis of 2, 3-Seco-24, 28-dinorlupa-4 (23), 20 (29)-diene-2, 17-dicarbonitrile

EF Khusnutdinova, IP Baikova, AN Lobov… - Russian Journal of …, 2021 - Springer
Abstract The oxidation of 2, 3-seco-24, 28-dinorlupa-4 (23), 20 (29)-diene-2, 17-
dicarbonitrile with ozone in methylene chloride at–40° C afforded a mixture of 4, 20-dioxo-2 …

Expanded scope of Griesbaum co-ozonolysis for the preparation of structurally diverse sensors of ferrous iron

J Chen, RL Gonciarz, AR Renslo - RSC advances, 2021 - pubs.rsc.org
Sterically shielded 1, 2, 4-trioxolanes prepared by Griesbaum co-ozonolysis have been
utilized as chemical sensors of ferrous iron in several recently described chemical probes of …

Criegee‐Intermediate über die Ozonolyse hinaus: Ein Einblick in Synthesen und Mechanismen

Z Hassan, M Stahlberger, N Rosenbaum… - Angewandte …, 2021 - Wiley Online Library
Mehr als 70 Jahre nach der Entdeckung sind die “Criegee‐Intermediate”(CIs) wieder an der
Spitze der modernen Chemie kurzlebiger reaktiver Zwischenprodukte angelangt. Sie …