Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Visible light photoredox-catalysed remote C–H functionalisation enabled by 1, 5-hydrogen atom transfer (1, 5-HAT)

W Guo, Q Wang, J Zhu - Chemical Society Reviews, 2021 - pubs.rsc.org
The generation of heteroatom-centred radicals (X˙), followed by intramolecular 1, 5-
hydrogen atom transfer (1, 5-HAT) and the functionalisation of the translocated carbon …

Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives

WM Cheng, R Shang - ACS Catalysis, 2020 - ACS Publications
The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals

S Sarkar, KPS Cheung, V Gevorgyan - Chemical Science, 2020 - pubs.rsc.org
Selective functionalization of ubiquitous unactivated C–H bonds is a continuous quest for
synthetic organic chemists. In addition to transition metal catalysis, which typically operates …

Photocatalytic C (sp 3) radical generation via C–H, C–C, and C–X bond cleavage

CY Huang, J Li, CJ Li - Chemical Science, 2022 - pubs.rsc.org
C (sp3) radicals (R˙) are of broad research interest and synthetic utility. This review collects
some of the most recent advancements in photocatalytic R˙ generation and highlights …

Catalysis with palladium complexes photoexcited by visible light

P Chuentragool, D Kurandina… - Angewandte Chemie …, 2019 - Wiley Online Library
Palladium catalysis induced by visible light is an emerging field of catalysis. In contrast to
classical reactions catalyzed by Pd complexes in the ground state, which mostly proceed …

Three-component, interrupted radical Heck/allylic substitution cascade involving unactivated alkyl bromides

HM Huang, P Bellotti, PM Pflüger… - Journal of the …, 2020 - ACS Publications
Developing efficient and selective strategies to approach complex architectures containing
(multi) stereogenic centers has been a long-standing synthetic challenge in both academia …

Visible-Light-Catalyzed Tandem Radical Addition/1, 5-Hydrogen Atom Transfer/Cyclization of 2-Alkynylarylethers with Sulfonyl Chlorides

L Li, JZ Li, YB Sun, CM Luo, H Qiu, K Tang, H Liu… - Organic …, 2022 - ACS Publications
A novel visible-light-catalyzed tandem radical addition/1, 5-hydrogen atom
transfer/cyclization cascade of 2-alkynylarylethers with sulfonyl chlorides in 2 …

Pd (0)/blue light promoted carboiodination reaction–evidence for reversible C–I bond formation via a radical pathway

AD Marchese, AG Durant, CM Reid… - Journal of the …, 2022 - ACS Publications
A Pd (0)/blue light catalyzed carboiodination reaction is reported. A simple, air-stable
catalytic system, utilizing [Pd (allyl) Cl] 2 and DPEPhos, generated a variety of iodinated …