This minireview summarizes synthetic approaches towards homoleptic dirhodium (II, II)
paddlewheel complexes with the general formula Rh2A4. These complexes have found …

Conspectus Rh2L4 catalysts have risen in popularity in the world of organic synthesis, being
used to accomplish a variety of reactions, including C–H insertion and cyclopropanation …

Described herein is an enantioselective dirhodium (II)-catalyzed cycloisomerization of
diynes achieved by the strategy of desymmetrization, which not only represents a new …

An electron rich Ni (I)–Ni (I) bond supported by a doubly reduced naphthyridine–diimine
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …

The enantioselective amination of C (sp 3)–H bonds is a powerful synthetic transformation
yet highly challenging to achieve in an intermolecular sense. We have developed a family of …

The functionalization of C− H bonds with non‐precious metal catalysts is an important
research area for the development of efficient and sustainable processes. Herein, we …

The photolysis of diazoalkanes is a timely strategy to conduct carbene‐transfer reactions
under mild and metal‐free reaction conditions, and has developed as an important …

Air-stable square pyramidal copper (II) bromide complexes 1, 2 and 3 with NNS, N (NH) S
and NNO ligand frameworks, respectively, were synthesized and successfully utilized as …

Density functional theory calculations were used to systematically explore the effects of axial
ligation by solvent molecules on the reactivity and selectivity of dirhodium tetracarboxylates …

Dirhodium (II) paddlewheel complexes have high utility in diazo-mediated cyclopropanation
reactions and ethyl diazoacetate is one of the most commonly used diazo compounds in this …