Multimetallic catalysis based on heterometallic complexes and clusters
P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …
transformation. It has witnessed rapidly increasing developments during the past decades in …
Investigations of tri-t-butyl tin hydride complexes of transition metals in small molecule activation and catalysis
Transition metal complexes containing the sterically encumbered SnBu t 3 group are the
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
Iridium–bismuth cluster complexes yield bimetallic nano-catalysts for the direct oxidation of 3-picoline to niacin
RD Adams, M Chen, G Elpitiya, ME Potter, R Raja - ACS Catalysis, 2013 - ACS Publications
The reaction of Ir3 (CO) 9 (μ3-Bi), 1, with BiPh3 has yielded a iridium–bismuth cluster
complex Ir5 (CO) 10 (μ3-Bi) 2 (μ4-Bi), 2. The first examples of bimetallic iridium–bismuth …
complex Ir5 (CO) 10 (μ3-Bi) 2 (μ4-Bi), 2. The first examples of bimetallic iridium–bismuth …
Unraveling the effect of ZrO 2 modifiers on the nature of active sites on AuRu/ZrO 2 catalysts for furfural hydrogenation
S Morandi, M Manzoli, CE Chan-Thaw… - Sustainable Energy & …, 2020 - pubs.rsc.org
Ru and AuRu nanoparticles were prepared by a sol-immobilization methodology and
deposited on different doped zirconia supports (ZrO2, Y–ZrO2 and La–ZrO2). The catalysts …
deposited on different doped zirconia supports (ZrO2, Y–ZrO2 and La–ZrO2). The catalysts …
Synthesis, structural elucidation, and catalytic activity of bimetallic rhenium-tin complexes containing Schiff base ligand
Novel bimetallic systems with Re and Sn metals, containing Schiff base linker were
designed and explored for their cooperative effect in the catalysis. ReSn bimetallic …
designed and explored for their cooperative effect in the catalysis. ReSn bimetallic …
Synthesis and structural characterization of ruthenium carbonyl cluster complexes containing platinum with a bulky N-heterocyclic carbene ligand
The reaction of Ru3 (CO) 12 with Pt (IMes) 2 in benzene solvent at room temperature
afforded the monoplatinum–triruthenium cluster complex Ru3Pt (IMes) 2 (CO) 11, 1, in 21 …
afforded the monoplatinum–triruthenium cluster complex Ru3Pt (IMes) 2 (CO) 11, 1, in 21 …
Supported bimetallic AuPd nanoparticles as a catalyst for the selective hydrogenation of nitroarenes
The solvent-free selective hydrogenation of nitrobenzene was carried out using a supported
AuPd nanoparticles catalyst, prepared by the modified impregnation method (MIm), as …
AuPd nanoparticles catalyst, prepared by the modified impregnation method (MIm), as …
Pendant Alkyl and Aryl Groups on Tin Control Complex Geometry and Reactivity with H2/D2 in Pt(SnR3)2(CNBut)2 (R = But, Pri, Ph, Mesityl)
The complex Pt (SnBut3) 2 (CNBut) 2 (H) 2, 1, was obtained from the reaction of Pt (COD) 2
and But3SnH, followed by addition of CNBut. The two hydride ligands in 1 can be …
and But3SnH, followed by addition of CNBut. The two hydride ligands in 1 can be …
Stoichiometric molecular single source precursors to cobalt phosphides
P Buchwalter, J Rosé, B Lebeau, P Rabu… - Inorganica Chimica …, 2014 - Elsevier
Crystalline cobalt phosphides were synthesized by using three different, low oxidation-state
organometallic clusters as precursors,[Co 4 (CO) 10 (μ-dppa)],[Co 4 (CO) 10 (μ 4-PPh) 2] …
organometallic clusters as precursors,[Co 4 (CO) 10 (μ-dppa)],[Co 4 (CO) 10 (μ 4-PPh) 2] …
Mixed-Metal Cluster Complexes from the Reactions of M3(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)(SnBut3)(H)
The reaction of Ru 3 (CO) 12 with Pt (IPr)(SnBu t 3)(H) at 68° C yielded the trigonal
bipyramidal cluster Ru 3 Pt 2 (IPr) 2 (CO) 12, 1, in 32% yield. The reaction of Os 3 (CO) 12 …
bipyramidal cluster Ru 3 Pt 2 (IPr) 2 (CO) 12, 1, in 32% yield. The reaction of Os 3 (CO) 12 …