Recent contributions from the Baylis− Hillman reaction to organic chemistry

D Basavaiah, BS Reddy, SS Badsara - Chemical reviews, 2010 - ACS Publications
Organic synthesis is one of the most successful and useful disciplines of science and mainly
involves the construction of carbon-carbon bond (s) and carbon-heteroatom bond (s) and …

aza-Baylis−Hillman Reaction

V Declerck, J Martinez, F Lamaty - Chemical Reviews, 2009 - ACS Publications
The creation of carbon-carbon bonds remains an important challenge in organic synthesis.
Numerous reactions for the formation of carbon-carbon bonds have been discovered and …

The Baylis–Hillman reaction: a novel source of attraction, opportunities, and challenges in synthetic chemistry

D Basavaiah, KV Rao, RJ Reddy - Chemical Society Reviews, 2007 - pubs.rsc.org
The Baylis–Hillman reaction is a successful, useful, and atom-economical carbon–carbon
bond forming reaction, which has grown from an obscure level to the level of high synthetic …

Advances in the Baylis–Hillman reaction-assisted synthesis of cyclic frameworks

V Singh, S Batra - Tetrahedron, 2008 - Elsevier
Acquiring the capability to access structurally complex and diverse molecules through
simple starting substrates has been one of the underlying principles of chemical research …

π‐Lewis‐Base‐Catalyzed Asymmetric Vinylogous Umpolung Reactions of Cyclopentadienones and Tropone

XX Yang, RJ Yan, GY Ran, C Chen… - Angewandte Chemie …, 2021 - Wiley Online Library
We disclose that the carbonates of 4‐hydroxy‐2‐cyclopentenones can form π‐allylpalladium‐
based 1, 2‐carbodipoles, which isomerize to interesting η2‐Pd0‐cyclopentadienone …

Cycloadditions and cyclizations of acetylenic, allenic, and conjugated dienyl sulfones

TG Back, KN Clary, D Gao - Chemical reviews, 2010 - ACS Publications
Sulfones display a diverse range of behavior and possess unique features that make them
valuable for numerous types of synthetic applications. As a result of their utility and …

Palladium‐Catalyzed Inverse and Normal Dehydrogenative Aza‐Morita–Baylis–Hillman Reactions with γ, δ‐Unsaturated Compounds

P Chen, SZ Tan, L Zhu, Q Ouyang, ZJ Jia… - Angewandte …, 2023 - Wiley Online Library
Abstract σ‐Lewis base‐catalyzed regio‐and enantioselective aza‐Morita–Baylis–Hillman
(MBH) reaction of α, β, γ, δ‐unsaturated systems remains a challenge due to the intrinsic …

Palladium (0) π-Lewis Base Catalysis: Concept and Development

ZC Chen, Q Ouyang, W Du… - Journal of the American …, 2024 - ACS Publications
The development of a new catalytic strategy plays a vital role in modern organic chemistry
since it permits bond formation in an unprecedented and more efficient manner. Although …

Aza‐Baylis–Hillman Reactions and Their Synthetic Applications

YL Shi, M Shi - European journal of organic chemistry, 2007 - Wiley Online Library
Abstract Aza‐Baylis–Hillman reactions have attracted much attention over the past decade.
This review concentrates on discussion of the origins of and progress in aza‐Baylis–Hillman …

Aza-Morita− Baylis− Hillman reactions and cyclizations of conjugated dienes activated by sulfone, ester, and keto groups

JM Sorbetti, KN Clary, DA Rankic, JE Wulff… - The Journal of …, 2007 - ACS Publications
The aza-Morita− Baylis− Hillman reactions of aldimines 2 with several activated conjugated
dienes were found to proceed smoothly in DMF in the presence of 3-hydroxyquinuclidine …