Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality

S Bhattacharyya, TK Maji - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …

Tailoring a robust Al-MOF for trapping C 2 H 6 and C 2 H 2 towards efficient C 2 H 4 purification from quaternary mixtures

S Laha, N Dwarkanath, A Sharma, D Rambabu… - Chemical …, 2022 - pubs.rsc.org
Light hydrocarbon separation is considered one of the most industrially challenging and
desired chemical separation processes and is highly essential in polymer and chemical …

Nanospace Engineering for C8 Aromatic Isomer Separation

N Zhu, J Wu, D Zhao - ACS nano, 2025 - ACS Publications
C8 aromatic isomers, namely para-xylene (PX), meta-xylene (MX), ortho-xylene (OX), and
ethylbenzene (EB), are essential industrial chemicals with a wide range of applications. The …

Electron Rich Guest Regulated Enhanced CO2 Reduction in a Multivariate Porous Coordination Polymer

R Jena, FA Rahimi, S Karmakar, A Dey… - Advanced Functional …, 2024 - Wiley Online Library
The need for carbon‐neutralization technologies has prompted significant interest in
developing materials for CO2 reduction. Donor–acceptor (D–A) based flexible porous …

A gating ultramicroporous metal-organic framework showing high adsorption selectivity, capacity and rate for xylene separation

ZM Ye, XF Zhang, DX Liu, YT Xu, C Wang… - Science China …, 2022 - Springer
Adsorptive separation of p-xylene (p X) from xylene isomers is a key process in chemical
industry, but known adsorbents cannot simultaneously achieve high adsorption selectivity …

Switching Adsorbent Layered Material that Enables Stepwise Capture of C8 Aromatics via Single-Crystal-to-Single-Crystal Transformations

MY Gao, SQ Wang, AA Bezrukov, S Darwish… - Chemistry of …, 2023 - ACS Publications
Separation of the C8 aromatic isomers, xylenes (PX, MX, and OX) and ethylbenzene (EB), is
important to the petrochemical industry. Whereas physisorptive separation is an energy …

Tunable Crystalline Organic Cage for Selective Sorting of Ortho-Monohalotoluene Isomers

LO Alimi, B Moosa, W Lin, NM Khashab - ACS Materials Letters, 2024 - ACS Publications
A highly flexible 4, 4′-oxybis benzaldehyde-based imine cage (Oba-cage) has selectively
adsorbed the ortho-isomer from all other monohalotoluene (X-toluene, X= F, Cl, and Br) …

Isomer recognition by dynamic guest-adaptive ligand rotation in a metal–organic framework with local flexibility

YJ Zhao, WQ Tang, XW Wang, HF Zhao, ZY Gu… - Chemical …, 2022 - pubs.rsc.org
Local flexibility in a metal–organic framework is intriguing for reconstructing a
microenvironment to distinguish different guest molecules by emphasizing their differences …

Adsorption Mechanism of Benzene Derivatives by Pagoda[n]arenes

Z Xi, Z Yang, X Zhang, H Yuan, W Wang… - …, 2023 - Wiley Online Library
Despite the widespread use in industrial production, benzene derivatives are harmful to both
human beings and the environment. The control of these substances has become an …

Crystalline nanosheets of three-dimensional supramolecular frameworks with uniform thickness and high stability

X Wang, Y Jin, T Zheng, N Li, Y Han, B Yu, K Wang… - Chemical …, 2024 - pubs.rsc.org
Fabricating three dimensional (3D) supramolecular frameworks (SMFs) into stable
crystalline nanosheets remains a great challenge due to the homogeneous and weak inter …