The reactions of dimethyl carbonate and its derivatives

P Tundo, M Musolino, F Aricò - Green chemistry, 2018 - pubs.rsc.org
The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry
and academia to develop of chlorine-free methodologies focused on the use of CO2 and …

Dimethyl carbonate as a modern green reagent and solvent

F Aricò, P Tundo - Russian Chemical Reviews, 2010 - iopscience.iop.org
Published data on dimethyl carbonate as a safe reagent and solvent in organic synthesis
are generalized and analyzed. The methods of dimethyl carbonate preparation and its use …

Acid-catalysed reactions of amines with dimethyl carbonate

P Worsawat, P Noppawan, C Croise… - Organic & …, 2023 - pubs.rsc.org
Highly effective acid-catalysed reactions of amines with dimethyl carbonate (DMC) have
been conducted with significant yields and selectivity of carboxymethylation or methylation …

Reaction Pathways in Carbonates and Esters

P Tundo, F Arico - ChemSusChem, 2023 - Wiley Online Library
This review reports on the competition/collaboration among intertwined base‐catalyzed acyl
cleavage bimolecular mechanism (BAc2)/base‐catalyzed alkyl cleavage bimolecular …

Fast synthesis of crosslinked self-blowing poly (β-hydroxythioether) foams by decarboxylative-alkylation of thiols at room temperature

S El Khezraji, SG Tomé, S Thakur, EH Ablouh… - European Polymer …, 2023 - Elsevier
A novel strategy was developed to prepare a self-blowing poly (β-hydroxythioether) foam at
room temperature by S-alkylation of 5-membered bis-cyclic carbonate using multifunctional …

Dimethyl carbonate via transesterification of propylene carbonate with methanol over ion exchange resins

A Pyrlik, WF Hoelderich, K Müller, W Arlt… - Applied Catalysis B …, 2012 - Elsevier
The transesterification of propylene carbonate with methanol to form dimethyl carbonate has
been carried out in the presence of strong basic ion exchange resins as heterogeneous …

Highly selective phosgene-free carbamoylation of aniline by dimethyl carbonate under continuous-flow conditions

S Grego, F Aricò, P Tundo - Organic Process Research & …, 2013 - ACS Publications
Over the last 20 years organic carbamates have found numerous applications in pesticides,
fungicides, herbicides, dyes, pharmaceuticals, cosmetics, and as protecting groups and …

Reaction of the ambident electrophile dimethyl carbonate with the ambident nucleophile phenylhydrazine

AE Rosamilia, F Arico, P Tundo - The Journal of Organic …, 2008 - ACS Publications
To explore the ambident electrophilic reactivity of dimethyl carbonate (DMC), reactions with
the ambident nucleophile phenylhydrazine were investigated. When a Brönsted base was …

Zinc acetates as efficient catalysts for the synthesis of bis-isocyanate precursors

E Reixach, N Bonet, FX Rius-Ruiz… - Industrial & engineering …, 2010 - ACS Publications
Anhydrous and hydrated zinc acetates were found to efficiently catalyze alkoxycarbonylation
of the aromatic diamines 2, 4-toluenediamine (2, 4-TDA) and 4, 4′-diphenylmethane …

Layered Double Hydroxide‐Supported L‐Methionine‐Catalyzed Chemoselective O‐Methylation of Phenols and Esterification of Carboxylic Acids with Dimethyl …

A Dhakshinamoorthy, A Sharmila… - … –A European Journal, 2010 - Wiley Online Library
Alkylation of aromatics, an important reaction in organic chemistry, is widely used in the
synthesis of petrochemicals, fine chemicals and pharmaceuticals.[1–4] Methyl halides …