Meerwein-Ponndorf-Verley reductions and Oppenauer oxidations: an integrated approach

CF De Graauw, JA Peters, H Van Bekkum… - Synthesis, 1994 - thieme-connect.com
Several heterogeneous systems have been developed, with advan-tages like easy catalyst
handling, workup, and recycling. Here again, lanthanide and zirconium catalysts seem very …

Gas-phase reactions of lanthanide cations with alcohols

JM Carretas, J Marçalo, AP de Matos - International Journal of Mass …, 2004 - Elsevier
The gas-phase reactions of the lanthanide series cations Ln+ (Ln= La–Lu, except Pm) with
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …

Gas‐phase transuranium chemistry: reactions of actinide ions with alcohols and thiols

JK Gibson - Journal of mass spectrometry, 1999 - Wiley Online Library
The laser ablation with prompt reaction and detection method was employed to provide a
survey of some gas‐phase reactions of actinide (M= U, Np, Pu and Am) and lanthanide (M …

Gas-phase reactions of Sc+, Y+, and Lu+ with alcohols. Effects of the class and chain length of alcohols on the nature of primary products

S Géribaldicor, S Breton, M Decouzon… - Journal of the American …, 1996 - Springer
The primary gas-phase reactions between methanol, ethanol, propan-1-ol, propan-2-ol, and
2-methyipropan-2-ol and the isovalent rare earth metal ions Sc+, Y+, and Lu+ generated by …

Structural characterization and reactivity studies of the samarium aryloxide complex Sm (O-2, 6-Pr2iC6H3) 3 (THF) 2

DL Clark, JC Gordon, JG Watkin, JC Huffman… - Polyhedron, 1996 - Elsevier
Reaction of the samarium aryloxide bis-THF adduct Sm (OAr) 3 (THF) 2 (1; Ar= 2, 6-
Pr2iC6H3) with two equivalents of pyridine produces the bis-pyridine complex Sm (OAr) …

Chiral induction in lanthanide (III)‐alkoxide‐catalysed Meerwein‐Ponndorf‐Verley reductions

J Huskens, CF de Graauw, JA Peters… - Recueil des Travaux …, 1994 - Wiley Online Library
The reduction of acetophenone using a chiral catalyst, prepared in situ by adding a chiral
dihydroxy compound to a solution of a lanthanide (III) alkoxide, was studied. The highest …

Competitive cryochemical reactions of transition metal atoms, clusters and nanosized particles

TI Shabatina, J Mascetti, JS Ogden… - Russian Chemical …, 2007 - iopscience.iop.org
Specific features of cryochemical reactions of transition metal atoms, small clusters,
complexes and nanoparticles are considered. New phenomena that arise in nano-and …

Thedissolution'of europium and ytterbium in alcohols

JM Carretas, J Branco, J Marçalo… - Journal of alloys and …, 1998 - Elsevier
Directdissolution'of metallic europium and ytterbium in alcohols, without the use of a catalyst,
was studied. In this work we report the reactions with methanol, ethanol and isopropanol …

Synthesis and characterization of polynuclear lanthanide aryloxides

J Carretas, J Branco, J Marçalo, P Isolani… - Journal of alloys and …, 2001 - Elsevier
The reactions of europium and ytterbium in liquid ammonia with a solution of 1-naphthol in
tetrahydrofuran provide a convenient route to lanthanide aryloxides. The polymetallic …

Europium (II) and ytterbium (II) aryloxide chemistry: synthesis and crystal structure of [Eu (OC6H3But2-2, 6) 2 (THF) 3]· 0.75 C7H8 and [Yb (OC6H3But2-2, 6) 2 (NCMe) …

J Carretas, J Branco, J Marçalo, Â Domingos… - Polyhedron, 2003 - Elsevier
The reactions of europium and ytterbium with 2, 6-di-tert-butylphenol were studied by the
metal vapour synthesis technique and by dissolution in liquid ammonia. The lanthanide …