Methods of reactivity umpolung

D Seebach - Angewandte Chemie International Edition in …, 1979 - Wiley Online Library
The past decade of organic chemistry may be charcterized as a period of violent
development of new synthetic methods. This was accompained by a systematization of the …

New developments in the chemistry of low‐valent titanium

A Fürstner, B Bogdanović - Angewandte Chemie International …, 1996 - Wiley Online Library
Among the applications of low‐valent titanium in organic synthesis, the reductive coupling of
carbonyl compounds to produce alkenes (the McMurry reaction) is particularly prominent …

Transition metal-promoted free-radical reactions in organic synthesis: the formation of carbon-carbon bonds

J Iqbal, B Bhatia, NK Nayyar - Chemical Reviews, 1994 - ACS Publications
The formation of a carbon-carbon bond using free radicals has ushered a new era1-8 in the
domain of synthetic organic chemistry. This development, which took place during the last …

Methoden der Reaktivitätsumpolung

D Seebach - Angewandte Chemie, 1979 - Wiley Online Library
In den letzten zehn Jahren haben sich die organisch‐chemischen Synthesemethoden
stürmisch entwickelt. Parallel dazu ist die Analyse synthetischer Probleme systematisiert …

[图书][B] CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2

WM Horspool, F Lenci - 2003 - taylorfrancis.com
The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to. alpha.,. beta.-enones. A New method of stereoselective introduction of the angular …

A Hosomi, H Sakurai - Journal of the American Chemical Society, 1977 - ACS Publications
Allylsilanes are interesting synthetic intermediates with highly nucleophilic double bonds, 2
and recently we have demonstrated that the allyl transferreaction takes place very smoothly …

Titanium-induced reductive coupling of carbonyls to olefins

JE McMurry, MP Fleming, KL Kees… - The Journal of Organic …, 1978 - ACS Publications
Active titanium metal, produced in a finely divided form by reduction of TiCl3 with either
potassium or lithium, will reductively couple ketones and aldehydes to olefins. Although the …

“Asymmetric” catalysis by lanthanide complexes

K Mikami, M Terada… - Angewandte Chemie …, 2002 - Wiley Online Library
Catalysis with lanthanide (Ln) complexes has been underestimated for long time, although
LnIII complexes have great advantages as Lewis acid catalysts for “asymmetric” carbon …

Carbonyl coupling reactions using transition metals, lanthanides, and actinides

BE Kahn, RD Rieke - Chemical Reviews, 1988 - ACS Publications
The use of metals in carbon-carbon bond forming reactions is well-known. Recent advances
in organo-metallic chemistry have produced many useful and highly specific carbon-carbon …

Organic reactions at alumina surfaces

GH Posner - Angewandte Chemie International Edition in …, 1978 - Wiley Online Library
Recent examples are given to emphasize that alumina can cause many different and often
unexpected chemical reactions of adsorbed organic molecules. Recent developments are …