P-Stereogenic phosphorus ligands in asymmetric catalysis

T Imamoto - Chemical reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Applications and stereoselective syntheses of P-chirogenic phosphorus compounds

M Dutartre, J Bayardon, S Jugé - Chemical Society Reviews, 2016 - pubs.rsc.org
Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers

A Nakamura, TMJ Anselment, J Claverie… - Accounts of chemical …, 2013 - ACS Publications
Ligands, Lewis bases that coordinate to the metal center in a complex, can completely
change the catalytic behavior of the metal center. In this Account, we summarize new …

Transition-metal-catalyzed functional polyolefin synthesis: effecting control through chelating ancillary ligand design and mechanistic insights

BP Carrow, K Nozaki - Macromolecules, 2014 - ACS Publications
The incorporation of polar functional groups into polyolefins can significantly alter the
adhesion, barrier and surface properties, dyeability, printability, and compatibility of the …

Photodegradable polar-functionalized polyethylenes

C Wang, J Xia, Y Zhang, X Hu… - National Science Review, 2023 - academic.oup.com
The degradation of plastics has attracted much attention from the global community.
Polyethylenes (PEs), as the most abundant synthetic plastics, are most frequently studied …

[HTML][HTML] Evolution in heterodonor PN, PS and PO chiral ligands for preparing efficient catalysts for asymmetric catalysis. From design to applications

J Margalef, M Biosca, P de la Cruz Sanchez… - Coordination Chemistry …, 2021 - Elsevier
The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

Quantification of the steric influence of alkylphosphine–sulfonate ligands on polymerization, leading to high-molecular-weight copolymers of ethylene and polar …

Y Ota, S Ito, J Kuroda, Y Okumura… - Journal of the American …, 2014 - ACS Publications
A series of palladium/alkylphosphine–sulfonate catalysts were synthesized and examined in
the homopolymerization of ethylene and the copolymerization of ethylene and polar …

A bulky Pd (II) α-diimine catalyst supported on sulfated zirconia for the polymerization of ethylene and copolymerization of ethylene and methyl acrylate

DB Culver, H Tafazolian, MP Conley - Organometallics, 2018 - ACS Publications
The reaction of (N∧ N) PdMe2 (N∧ N is Ar–N═ CMeMeC═ N–Ar; Ar= 2, 6-bis
(diphenylmethyl)-4-methylbenzene) and sulfated zirconia (SZO) in diethyl ether forms …

Highly selective cascade C–C bond formation via palladium-catalyzed oxidative carbonylation–carbocyclization–carbonylation–alkynylation of enallenes

C Zhu, B Yang, JE Backvall - Journal of the American Chemical …, 2015 - ACS Publications
A highly efficient palladium-catalyzed oxidative cascade reaction of enallenes undergoing
overall four C–C bond formations has been developed. The insertion cascade proceeds via …

[PDF][PDF] Nuclear magnetic resonance spectroscopy

CD Ridge - 2022 - toc.library.ethz.ch
Resonance Spectroscopy Page 1 Nuclear Magnetic Resonance Spectroscopy An Introduction
to Principles, Applications, and Experimental Methods Joseph B. Lambert Trinity University …