Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

A biphase H 2 O/CO 2 system as a versatile reaction medium for organic synthesis

MA Pigaleva, IV Elmanovich, YN Kononevich… - RSC …, 2015 - pubs.rsc.org
We review activity on the usage of a biphase H2O/CO2 system in organic synthesis as a
reaction medium of green chemistry. The formation of self-neutralizing carbonic acid in such …

Mechanochemistry–a new powerful green approach to the direct synthesis of alkoxysilanes

MN Temnikov, AA Anisimov, PV Zhemchugov… - Green …, 2018 - pubs.rsc.org
The present work shows a new one-stage mechanochemical method for the direct synthesis
of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol …

Перспективные точки роста и вызовы элементоорганической химии

ГА Абакумов, АВ Пискунов, ВК Черкасов… - Успехи химии, 2018 - mathnet.ru
Химия элементоорганических соединений в настоящее время—одна из самых
динамично развивающихся научных областей как в плане фундаментальных …

Hydrolytic polycondensation of diethoxymethylsilane under pressure

AA Kalinina, TA Pryakhina, EV Talalaeva… - Russian Chemical …, 2022 - Springer
The process of hydrolytic polycondensation of diethoxymethylsilane in water under pressure
was investigated without the use of organic solvents in non-catalytic conditions and in …

Synthesis of Multifunctional Oligomethylsilsesquioxanes by Catalyst-Free Hydrolytic Polycondensation of Methyltrimethoxysilane under Microwave Radiation

AA Kalinina, OB Gorbatsevich, NG Yakhontov… - Polymers, 2023 - mdpi.com
The catalyst-free hydrolytic polycondensation of methyltrimethoxysilane under microwave
radiation has been studied. The effect of molar ratios of the reagents (MTMS/H2O= 1/0.5 …

Organosilicon compounds in supercritical carbon dioxide: Synthesis, polymerization, modification, and production of new materials

MA Pigaleva, IV Elmanovich, MN Temnikov… - Polymer Science Series …, 2016 - Springer
The main promising opportunities for the advantageous combination of organosilicon
compounds and supercritical carbon dioxide both as a solvent and as a reagent in chemical …

Hydrolytic polycondensation of methylalkoxysilanes under pressure

AA Kalinina, DN Kholodkov, IB Meshkov… - Russian Chemical …, 2016 - Springer
Hydrolytic polycondensation of methytrialkoxysilanes under the pressure in water and in
carbonic acid was investigated. It is shown, that both processes proceed with full conversion …

Continuous dehydration of 1, 4-butanediol in flowing liquid water with carbon dioxide

O Sato, A Yamaguchi, M Shirai - Catalysis Communications, 2015 - Elsevier
Abstract Dehydration of 1, 4-butanediol to tetrahydrofuran in high-temperature liquid water
with carbon dioxide using a flow reactor system was studied. Tetrahydrofuran was …

Hydrolytic polycondensation of trimethoxymethylsilane under ultrasonic irradiation

NG Yakhontov, OB Gorbatsevich, AA Kalinina… - Mendeleev …, 2020 - Elsevier
The hydrolytic polycondensation of trimethoxymethylsilane in the absence of catalyst and
solvent under ultrasonic irradiation was performed, the effect of reagent ratio, power …