Switchable intrinsic defect chemistry of titania for catalytic applications

S Jayashree, M Ashokkumar - Catalysts, 2018 - mdpi.com
The energy crisis is one of the most serious issue that we confront today. Among different
strategies to gain access to reliable fuel, the production of hydrogen fuel through the water …

Introducing catalysis in photocatalysis: what can be understood from surface science studies of alcohol photoreforming on TiO2

CA Walenta, M Tschurl, U Heiz - Journal of Physics: Condensed …, 2019 - iopscience.iop.org
Mechanisms in heterogeneous photocatalysis have traditionally been interpreted by the
band-structure model and analogously to electrochemistry. This has led to the establishment …

Titanium Dioxide Nanoparticle Surface Reactivity with Atmospheric Gases, CO2, SO2, and NO2: Roles of Surface Hydroxyl Groups and Adsorbed Water in the …

CE Nanayakkara, WA Larish… - The Journal of Physical …, 2014 - ACS Publications
The reactivity of O–H groups on titanium dioxide nanoparticle surfaces with gas-phase
carbon dioxide, sulfur dioxide, and nitrogen dioxide is compared. Carbon dioxide, sulfur …

Surface Species in Photocatalytic Methanol Reforming on Pt/TiO2(110): Learning from Surface Science Experiments for Catalytically Relevant Conditions

CA Walenta, C Courtois, SL Kollmannsberger… - ACS …, 2020 - ACS Publications
Photocatalytic hydrogen evolution from methanol is a standard test reaction for photocatalyst
materials. Surprisingly, the exact chemical mechanism is still widely discussed in the …

Biomaterial-Induced Stable Resistive Switching Mechanism in TiO2 Thin Films: The Role of Active Interstitial Sites/Ions in Minimum Current Leakage and Superior …

MS Abbasi, MS Irshad, N Arshad, I Ahmed, M Idrees… - ACS …, 2020 - ACS Publications
Leakage of current in oxide layers is the main issue for higher speed and denser resistive
random-access memory. Defect engineering played a substantial role in meeting this …

Oxidative decomposition of dimethyl methylphosphonate on rutile TiO 2 (110): the role of oxygen vacancies

C Tesvara, C Walenta, P Sautet - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The decomposition of dimethyl methylphosphonate (DMMP,(CH3O) 2P (O)(CH3)), a
simulant to the toxic nerve agent Sarin, on the rutile TiO2 (110) surface has been studied …

Nanoscale Solvation Leads to Spontaneous Formation of a Bicarbonate Monolayer on Rutile (110) under Ambient Conditions: Implications for CO2 Photoreduction

A Song, ES Skibinski, WJI DeBenedetti… - The Journal of …, 2016 - ACS Publications
The chemical state of a catalyst in operando is particularly important for catalysts that target
minority species, such as atmospheric CO2 which has a concentration of only 400 ppm. A …

Bulk Defect Dependence of Low-Temperature Partial Oxidation of Methanol and High-Temperature Hydrocarbon Formation on Rutile TiO2 (110)

M Osmić, L Mohrhusen… - The Journal of Physical …, 2018 - ACS Publications
Titanium dioxide (TiO2) is among the most studied model (photo) catalyst materials. The
influence of surface point defects, like oxygen vacancies and particularly bulk defects such …

Nucleation and growth of Pt nanoparticles on reduced and oxidized rutile TiO2 (110)

F Rieboldt, LB Vilhelmsen, S Koust… - The Journal of …, 2014 - pubs.aip.org
The nucleation and growth of Pt nanoparticles (NP's) on rutile TiO 2 (110) surfaces with O on-
top atoms (oxidized TiO 2), surface O vacancies, and H adatoms, respectively (reduced TiO …

Atomic defects in titanium dioxide

T Minato - The Chemical Record, 2014 - Wiley Online Library
The functionality of solid materials is defined by the type and ordering of the constituent
atoms. By introducing defects that perturb the ordered structure, new functionality is created …