Active site identification and engineering during the dynamic evolution of copper-based catalysts for electrocatalytic CO2 reduction

B Deng, X Zhao, Y Li, M Huang, S Zhang… - Science China …, 2023 - Springer
To date, copper-based catalysts are one of the most prominent catalysts that can
electrochemically reduce CO2 towards high-value fuels or chemicals, such as ethylene …

A Review on the Influence of Crystal Facets on the Product Selectivity of CO2RR over Cu Metal Catalysts

D Ma, C Zhi, Y Zhang, J Chen, Y Zhang, JW Shi - ACS nano, 2024 - ACS Publications
The electrocatalytic carbon dioxide reduction reaction (ECRR) is promising in converting
environmentally harmful CO2 into useful chemicals, but the large-scale application of this …

Gerhardtite as a precursor to an efficient CO-to-acetate electroreduction catalyst

ZZ Wu, XL Zhang, PP Yang, ZZ Niu… - Journal of the …, 2023 - ACS Publications
Carbon–carbon coupling electrochemistry on a conventional copper (Cu) catalyst still
undergoes low selectivity among many different multicarbon (C2+) chemicals, posing a …

Correlating Oxidation State and Surface Area to Activity from Operando Studies of Copper CO Electroreduction Catalysts in a Gas-Fed Device

SH Lee, I Sullivan, DM Larson, G Liu, FM Toma… - ACS …, 2020 - ACS Publications
The rational design of high-performance electrocatalysts requires a detailed understanding
of dynamic changes in catalyst properties, including oxidation states, surface area, and …

Real-Time Detection of Acetaldehyde in Electrochemical CO Reduction on Cu Single Crystals

Y Qiao, D Hochfilzer, J Kibsgaard… - ACS Energy …, 2024 - ACS Publications
Copper is known to be versatile in producing various products from electrochemical CO2
reduction reaction (eCO2RR), and the product preference depends on reaction …

In situ analytical techniques for the investigation of material stability and interface dynamics in electrocatalytic and photoelectrochemical applications

S Pishgar, S Gulati, JM Strain, Y Liang… - Small …, 2021 - Wiley Online Library
Electrocatalysis and photoelectrochemistry are critical to technologies like fuel cells,
electrolysis, and solar fuels. Material stability and interfacial phenomena are central to the …

Revealing the Nature of C–C Coupling Sites on a Cu Surface for CO2 Reduction

M Song, Z Jiao, W Jing, Y Liu, L Guo - The Journal of Physical …, 2022 - ACS Publications
Electrochemical CO2 reduction technology plays an important role in reducing CO2 into
valuable chemical fuels. Therein, Cu-based catalysts show superior performance for …

Dramatic Change in the Step Edges of the Cu(100) Electrocatalyst upon Exposure to CO: Operando Observations by Electrochemical STM and Explanation Using …

S Kwon, YG Kim, JH Baricuatro, WA Goddard III - ACS Catalysis, 2021 - ACS Publications
Systematic structure–activity correlations in the electrochemical surface science of CO2
reduction (CO2R) are typically anchored on low Miller-index (hkl) surfaces with …

[HTML][HTML] Recent advances in single crystal and facet dependency of copper electrodes on electrochemical CO2 reduction

Y Qiao, B Seger - Current Opinion in Chemical Engineering, 2024 - Elsevier
Investigations on electrochemical CO 2 reduction reaction (eCO2RR) on copper (Cu)
provide instructive information for the understanding and development of Cu-based catalysts …

A New Look at Catalyst Surfaces at Work: Introducing Mixed Isotope Operando Infrared Spectroscopy (MIOIRS)

M Monai - ACS Catalysis, 2024 - ACS Publications
This Perspective focuses on the characterization of supported metal catalysts by operando
and CO infrared (IR) spectroscopy. CO IR spectroscopy is a powerful technique for probing …