Stereoselective synthesis of acyclic α,α-disubstituted α-amino acids derivatives from amino acids
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This review describes the recent advances in asymmetric reactions based on memory of
chirality. The memory of chirality is a unique concept concerning an advanced type of chiral …

Available α‐amino acids undergo arylation at their α position in an enantioselective manner
on treatment with base of N′‐aryl urea derivatives ligated to pseudoephedrine as a chiral …

Generation of helical and axial chirality has been the topic of much interest in biology and
chemistry. Controlling axial chirality with stereogenic-center-based chirality has shown to be …

Flow chemistry is a continually emerging and ever-growing area of synthetic organic
chemistry. It provides an orthogonal approach to traditional batch chemistry, oftentimes …

A new methodology for the asymmetric synthesis of quaternary α-substituted amino acids
using memory of chirality has been developed. The strategy utilizes the dynamic axial …

Open sesame! A selective metal‐catalyzed ring opening of alkylidenecyclopropane
derivatives leads to various functionalized acyclic derivatives possessing challenging …

Microreactor technology has proved to be an important technique in organic synthesis,
especially when organometallic compounds are used, because it allows running rapid …

GP-BAR1 (also known as TGR5), a novel G-protein coupled receptor regulating various non-
genomic functions via bile acid signaling, has emerged as a promising target for metabolic …

The cascade rearrangement of chiral enediynes 1c− e, involving successively 1, 3-proton
shift, Saito− Myers cyclization, 1, 5-hydrogen atom transfer, and intramolecular coupling of …