Polyhydroxyalkanoates (PHAs) are a unique class of commercially manufactured
biodegradable polyesters with properties suitable for partially substituting petroleum‐based …

The carbonylative polymerization of epoxides provides a promising but challenging strategy
to synthesize polyhydroxyalkanoates (PHAs) which are of high commercial value in the field …

The catalytic enantioselective syntheses of epoxides has been studied intensively over the
last three decades.[1] In striking contrast, there are few reports on the catalytic …

The development of biodegradable and recyclable polymers having the desired material
properties required in practical use has provided a partial solution for realizing a sustainable …

The almost centennary history of alkyl-and acylcobalt carbonyls started with preparative and
structural interest in these particular compounds, but the attention also soon included …

Zwitterionic structure is necessary for NiII complexes to catalyze carbonylative
polymerization (COP) of cyclic ethers. The cationic charge at the NiII center imparts sufficient …

Abstract γ‐butyrolactones and their derivatives serve as the fundamental building blocks for
a wide range of biologically significant and synthetically challenging natural products, which …

ABSTRACT Polyhydroxyalkanoate (PHA), a well-known biodegradable polymer, features β-
lactones as its monomers, which can be selectively synthesized through ring-expansion …

Abstract Poly (malic acid)(PMLA) is a water‐soluble, biodegradable, biocompatible, and
nontoxic polyester in the poly (hydroxyalkanoate)(PHA) family. it features various …

A catalyst-free novel and efficient methodology for the challenging synthesis of benzo-
oxetes from 2'-hydroxyacetophenones mediated by sulfuryl fluoride (SO 2 F 2) gas has been …