Spatially resolving lithiation in silicon–graphite composite electrodes via in situ high-energy x-ray diffraction computed tomography

DP Finegan, A Vamvakeros, L Cao, C Tan… - Nano …, 2019 - ACS Publications
Optimizing the chemical and morphological parameters of lithium-ion (Li-ion) electrodes is
extremely challenging, due in part to the absence of techniques to construct spatial and …

[HTML][HTML] Microstructural degradation of silicon electrodes during lithiation observed via operando X-ray tomographic imaging

OO Taiwo, JM Paz-García, SA Hall, TMM Heenan… - Journal of Power …, 2017 - Elsevier
Due to their high theoretical capacity compared to that of state-of-the-art graphite-based
electrodes, silicon electrodes have gained much research focus for use in the development …

Multiscale Multiphase Lithiation and Delithiation Mechanisms in a Composite Electrode Unraveled by Simultaneous Operando Small-Angle and Wide-Angle X-Ray …

CL Berhaut, DZ Dominguez, P Kumar, PH Jouneau… - ACS …, 2019 - ACS Publications
The (de) lithiation process and resulting atomic and nanoscale morphological changes of an
a-Si/c-FeSi2/graphite composite negative electrode are investigated within a Li-ion full cell …

4D analysis of the microstructural evolution of Si-based electrodes during lithiation: Time-lapse X-ray imaging and digital volume correlation

JM Paz-Garcia, OO Taiwo, E Tudisco… - Journal of Power …, 2016 - Elsevier
Silicon is a promising candidate to substitute or complement graphite as anode material in Li-
ion batteries due, mainly, to its high energy density. However, the lithiation/delithiation …

Electrochemical reaction of lithium with nanostructured silicon anodes: a study by in‐situ synchrotron X‐Ray diffraction and electron energy‐loss spectroscopy

F Wang, L Wu, B Key, XQ Yang, CP Grey… - Advanced Energy …, 2013 - Wiley Online Library
Silicon‐based anodes are an appealing alternative to graphite for lithium‐ion batteries
because of their extremely high capacity. However, poor cycling stability and slow kinetics …

Quantifying lithium concentration gradients in the graphite electrode of Li-ion cells using operando energy dispersive X-ray diffraction

KPC Yao, JS Okasinski, K Kalaga, IA Shkrob… - Energy & …, 2019 - pubs.rsc.org
Safe, fast, and energy efficient cycling of lithium ion batteries is desired in many practical
applications. However, modeling studies predict steep Li+ ion gradients in the electrodes …

Charge Dynamics Induced by Lithiation Heterogeneity in Silicon‐Graphite Composite Anodes

CL Berhaut, M Mirolo, DZ Dominguez… - Advanced Energy …, 2023 - Wiley Online Library
The reaction processes in Li‐ion batteries can be highly heterogeneous at the electrode
scale, leading to local deviations in the lithium content or local degradation phenomena. To …

Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries

P Pietsch, M Hess, W Ludwig, J Eller, V Wood - Scientific reports, 2016 - nature.com
We present an operando study of a lithium ion battery combining scanning X-ray diffraction
(SXRD) and synchrotron radiation X-ray tomographic microscopy (SRXTM) simultaneously …

Multimodal nanoscale tomographic imaging for battery electrodes

S Müller, M Lippuner, M Verezhak… - Advanced Energy …, 2020 - Wiley Online Library
Accurate representations of the 3D structure within a lithium‐ion battery are key to
understanding performance limitations. However, obtaining exact reconstructions of …

[HTML][HTML] Unveiling the role of electrode-level heterogeneity alleviated in a silicon-graphite electrode under operando microscopy

J Kim, MH Kim, Y Kim, MS Kim, A Choi, KM Jeong… - Energy Storage …, 2023 - Elsevier
Reaction heterogeneity is a crucial factor that influences the design of composite electrodes.
Silicon–graphite composites exhibit practical use as anodes, but the complex mechanisms …