Light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes

AY Kovalevsky, KA Bagley, JM Cole… - Inorganic …, 2003 - ACS Publications
The irradiation of ruthenium− sulfur dioxide complexes of general formula trans-[RuII (NH3)
4 (S O2) X] Y with laser light at low temperature results in linkage isomerization of SO2 …

The first photocrystallographic evidence for light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes

AY Kovalevsky, KA Bagley… - Journal of the American …, 2002 - ACS Publications
Light-induced metastable linkage isomers of trans-[Ru (NH3) 4Cl (SO2)] Cl and trans-[Ru
(NH3) 4 (H2O)(SO2)](C6H5SO3) 2 have been identified for the first time using …

Photoconversion bonding mechanism in ruthenium sulfur dioxide linkage photoisomers revealed by in situ diffraction

SO Sylvester, JM Cole, PG Waddell - Journal of the American …, 2012 - ACS Publications
Three new ruthenium–sulfur dioxide linkage photoisomeric complexes in the [Ru (NH3) 4
(SO2) X] Cl2· H2O family (X= pyridine (1); 3-chloropyridine (2); 4-chloropyridine (3)) have …

Phototriggered S→ O isomerization of a ruthenium-bound chelating sulfoxide

DP Butcher, AA Rachford, JL Petersen… - Inorganic …, 2006 - ACS Publications
We have prepared and characterized [Ru (bpy) 2 (OS)]+(bpy= 2, 2 '-bipyridine; OS= 2-
methylthiobenzoate) and the chelating sulfoxide S-[Ru (bpy) 2 (OSO)]+(OSO …

Photoinduced ligand isomerization in dimethyl sulfoxide complexes of ruthenium (II)

MK Smith, JA Gibson, CG Young… - European Journal of …, 2000 - Wiley Online Library
Upon exposure to sunlight or UV irradiation, a DMSO solution of [Ru (bpy) 2 (DMSO) 2]
2+(1)(bpy= 2, 2'‐bipyridine; DMSO= dimethyl sulfoxide) turns rapidly from yellow to red, but …

Synthesis and characterization of new halogen-tetramethylene sulfoxide-ruthenium (II) and ruthenium (III) complexes; crystal structure of cis-dichlorotetrakis …

E Alessio, B Milani, G Mestroni, M Calligaris… - Inorganica chimica …, 1990 - Elsevier
In this paper we report the synthesis and characterization of the following ruthenium (II) and
ruthenium (III) complexes with tetramethylene sulfoxide (TMSO): cis-RuCl 2 (TMSO) 4 (1) …

Turning off phototriggered linkage isomerizations in ruthenium dimethyl sulfoxide complexes

JJ Rack, AA Rachford, AM Shelker - Inorganic chemistry, 2003 - ACS Publications
We report on the spectroscopy, electrochemistry, and linkage isomerization in a family of [Ru
(tpy)(L2)(dmso)] z+ complexes (tpy is 2, 2 ': 6 ', 2 ''-terpyridine, dmso is dimethyl sulfoxide …

Photochromic ruthenium sulfoxide complexes: evidence for isomerization through a conical intersection

BA McClure, NV Mockus, DP Butcher Jr… - Inorganic …, 2009 - ACS Publications
The complexes [Ru (bpy) 2 (OS)](PF6) and [Ru (bpy) 2 (OSO)](PF6), where bpy is 2, 2′-
bipyridine, OS is 2-methylthiobenzoate, and OSO is 2-methylsulfinylbenzoate, have been …

Phototriggered Ru (II)− dimethylsulfoxide linkage isomerization in crystals and films

JJ Rack, JR Winkler, HB Gray - Journal of the American Chemical …, 2001 - ACS Publications
Photochromic materials are of interest because of their potential applications in optical
information storage devices. 1-4 Measurements on photochromic sodium nitroprusside (Na2 …

Ru–OSO Coordination Photogenerated at 100 K in Tetraammineaqua (sulfur dioxide) ruthenium (II)(±)-Camphorsulfonate

AE Phillips, JM Cole, T d'Almeida, KS Low - Inorganic Chemistry, 2012 - ACS Publications
The photoinduced O-bound coordination mode in RuSO2 complexes, previously observed
only at 13 K, has been generated at 100 K in tetraammineaqua (sulfur dioxide) ruthenium …