Structural, Vibrational, and Electronic Study of Sb2S3 at High Pressure

J Ibáñez, JA Sans, C Popescu… - The Journal of …, 2016 - ACS Publications
Antimony trisulfide (Sb2S3), found in nature as the mineral stibnite, has been studied under
compression at room temperature from a joint experimental and theoretical perspective. X …

Structural properties of Sb2S3 under pressure: evidence of an electronic topological transition

I Efthimiopoulos, C Buchan, Y Wang - Scientific reports, 2016 - nature.com
High-pressure Raman spectroscopy and x-ray diffraction of Sb2S3 up to 53 GPa reveals two
phase transitions at 5 GPa and 15 GPa. The first transition is evidenced by noticeable …

High-Pressure Studies of Bi2S3

I Efthimiopoulos, J Kemichick, X Zhou… - The Journal of …, 2014 - ACS Publications
The high-pressure structural and vibrational properties of Bi2S3 have been probed up to 65
GPa with a combination of experimental and theoretical methods. The ambient-pressure …

Phase transition mechanism and bandgap engineering of Sb2S3 at gigapascal pressures

Z Cui, K Bu, Y Zhuang, ME Donnelly, D Zhang… - Communications …, 2021 - nature.com
Earth-abundant antimony trisulfide (Sb2S3), or simply antimonite, is a promising material for
capturing natural energies like solar power and heat flux. The layered structure, held up by …

Pressure-induced electronic topological transition in Sb2S3

YA Sorb, V Rajaji, PS Malavi, U Subbarao… - Journal of Physics …, 2015 - iopscience.iop.org
We report the high-pressure vibrational properties and a pressure-induced electronic
topological transition in the wide bandgap semiconductor Sb 2 S 3 (E g= 1.7–1.8 eV) using …

Experimental Observation of the High Pressure Induced Substitutional Solid Solution and Phase Transformation in Sb2S3

Y Wang, Y Ma, G Liu, J Wang, Y Li, Q Li, J Zhang… - Scientific Reports, 2018 - nature.com
The substitutional solid solutions composed of group VA-VIA nonmetallic elements has
attracted considerable scientific interest since they provide a pressure-induced route to …

Structural phase transitions in Bi2Se3 under high pressure

Z Yu, L Wang, Q Hu, J Zhao, S Yan, K Yang… - Scientific Reports, 2015 - nature.com
Raman spectroscopy and angle dispersive X-ray diffraction (XRD) experiments of bismuth
selenide (Bi2Se3) have been carried out to pressures of 35.6 and 81.2 GPa, respectively, to …

Structural and vibrational study of BiSe under high pressure

R Vilaplana, D Santamaría-Pérez, O Gomis… - Physical Review B …, 2011 - APS
The structural and vibrational properties of bismuth selenide (Bi 2 Se 3) have been studied
by means of x-ray diffraction and Raman scattering measurements up to 20 and 30 GPa …

Pressure-induced irreversible metallization accompanying the phase transitions in

L Dai, K Liu, H Li, L Wu, H Hu, Y Zhuang, L Yang, C Pu… - Physical Review B, 2018 - APS
We have revealed S b 2 S 3 to have two phase transitions and to undergo metallization
using a diamond anvil cell at around 5.0, 15.0, and 34.0 GPa, respectively. These results …

A theoretical study of the Pnma and R 3 [combining macron] m phases of Sb 2 S 3, Bi 2 S 3, and Sb 2 Se 3

EL da Silva, JM Skelton… - Journal of Materials …, 2022 - pubs.rsc.org
We report a comparative theoretical study of the Pnma and Rm phases of Sb2S3, Bi2S3,
and Sb2Se3 close to ambient pressure. Our enthalpy calculations at 0 K show that at …