Chemistry–mechanics–geometry coupling in positive electrode materials: a scale-bridging perspective for mitigating degradation in lithium-ion batteries through …

DA Santos, S Rezaei, D Zhang, Y Luo, B Lin… - Chemical …, 2023 - pubs.rsc.org
Despite their rapid emergence as the dominant paradigm for electrochemical energy
storage, the full promise of lithium-ion batteries is yet to be fully realized, partly because of …

V2O5 as a versatile electrode material for postlithium energy storage systems

Q Fu, H Zhao, A Sarapulova, S Dsoke - Applied Research, 2023 - Wiley Online Library
Postlithium batteries have received intense attention as an alternative for large‐scale
electric energy storage systems due to their rich resources and low cost. Vanadium …

Lone but not alone: Precise positioning of lone pairs for the design of photocatalytic architectures

JV Handy, W Zaheer, ARM Rothfuss… - Chemistry of …, 2022 - ACS Publications
With current economic growth and consumption trends projected to bring about a precipitous
and rapid rise of the global temperature, the world stands at a crossroads with regards to …

Ultrahigh Effective Diffusion in Oxide by Engineering the Interfacial Transporter Channels

L Li, M Hu, C Hu, B Li, S Zhao, T Zhou, J Zhu, M Liu… - Nano Letters, 2023 - ACS Publications
Mass storage and removal in solids always play a vital role in technological applications
such as modern batteries and neuronal computations. However, they were kinetically limited …

Ultrafast Single‐Crystal‐to‐Single‐Crystal Transformation from Metal–Organic Framework to 2D Hydroxide

W Wang, Y Wang, R He, X Wang, Z Shen… - Advanced …, 2022 - Wiley Online Library
Abstract Single‐crystal‐to‐single‐crystal (SCSC) transformations have received
considerable interest in crystal engineering, owing to providing a key platform for creating …

Protecting groups in insertion chemistry: Site-selective positioning of lithium ions in intercalation hosts

JV Handy, W Zaheer, R Albers, G Agbeworvi, TD Boyko… - Matter, 2023 - cell.com
The expanding toolbox of functionalization chemistries for selectively installing moieties on
specific sites of a substrate underpins almost all modern organic and biochemical …

Effect of pre-intercalation on Li-ion diffusion mapped by topochemical single-crystal transformation and operando investigation

Y Luo, JV Handy, T Das, JD Ponis, R Albers… - Nature Materials, 2024 - nature.com
Limitations in electrochemical performance as well as supply chain challenges have
rendered positive electrode materials a critical bottleneck for Li-ion batteries. State-of-the-art …

Cation reordering instead of phase transitions: Origins and implications of contrasting lithiation mechanisms in 1D ζ- and 2D α-V2O5

Y Luo, S Rezaei, DA Santos, Y Zhang… - Proceedings of the …, 2022 - National Acad Sciences
Substantial improvements in cycle life, rate performance, accessible voltage, and reversible
capacity are required to realize the promise of Li-ion batteries in full measure. Here, we have …

Impact of structural deformations on the performance of Li-ion insertion hosts

JL Andrews, MJ Brady, ET McClure… - Chemistry of …, 2022 - ACS Publications
Over the course of more than three decades, Li-ion batteries have come to revolutionize the
way we store and transport energy. These incredibly compact electrochemical devices rely …

[PDF][PDF] Curvature-induced modification of mechano-electrochemical coupling and nucleation kinetics in a cathode material

JL Andrews, P Stein, DA Santos, CJ Chalker… - Matter, 2020 - cell.com
Intercalation-induced phase transformations in Li-ion battery electrode materials give rise to
multi-phase coexistence regimes within individual particles, generating significant lattice …