Designing catalysts for water splitting based on electronic structure considerations
The disproportionation of H 2 O into solar fuels H 2 and O 2, or water splitting, is a promising
strategy for clean energy harvesting and storage but requires the concerted action of …
strategy for clean energy harvesting and storage but requires the concerted action of …
[HTML][HTML] Chemistry–mechanics–geometry coupling in positive electrode materials: a scale-bridging perspective for mitigating degradation in lithium-ion batteries …
Despite their rapid emergence as the dominant paradigm for electrochemical energy
storage, the full promise of lithium-ion batteries is yet to be fully realized, partly because of …
storage, the full promise of lithium-ion batteries is yet to be fully realized, partly because of …
[PDF][PDF] Reversible Mg-ion insertion in a metastable one-dimensional polymorph of V2O5
The Li-ion paradigm of battery technology is constrained by the monovalency of the Li ion. A
straightforward solution is to transition to multivalent-ion chemistries, where Mg 2+ is the …
straightforward solution is to transition to multivalent-ion chemistries, where Mg 2+ is the …
Traversing energy landscapes away from equilibrium: strategies for accessing and utilizing metastable phase space
The known crystal structures of solids often correspond to the most thermodynamically
stable arrangement of atoms. Yet, oftentimes there exist a richly diverse set of alternative …
stable arrangement of atoms. Yet, oftentimes there exist a richly diverse set of alternative …
On the strange case of divalent ions intercalation in V2O5
Vanadium pentoxide has been investigated for multivalent ion battery technologies but the
structural characterization of inserted phases is poor, and conflicting reports exist in the …
structural characterization of inserted phases is poor, and conflicting reports exist in the …
Defining Diffusion Pathways in Intercalation Cathode Materials: Some Lessons from V2O5 on Directing Cation Traffic
The invention of rechargeable batteries has dramatically changed our landscapes and lives,
underpinning the explosive worldwide growth of consumer electronics, ushering in an …
underpinning the explosive worldwide growth of consumer electronics, ushering in an …
Cation reordering instead of phase transitions: Origins and implications of contrasting lithiation mechanisms in 1D ζ- and 2D α-V2O5
Substantial improvements in cycle life, rate performance, accessible voltage, and reversible
capacity are required to realize the promise of Li-ion batteries in full measure. Here, we have …
capacity are required to realize the promise of Li-ion batteries in full measure. Here, we have …
Reciprocal space imaging of ionic correlations in intercalation compounds
MJ Krogstad, S Rosenkranz, JM Wozniak… - Nature materials, 2020 - nature.com
The intercalation of alkali ions into layered materials has played an essential role in battery
technology since the development of the first lithium-ion electrodes. Coulomb repulsion …
technology since the development of the first lithium-ion electrodes. Coulomb repulsion …
Dual-stage K+ ion intercalation in V 2 O 5-conductive polymer composites
We reported that the incorporation of a conductive polymer into V2O5 materials resulted in
an increased interlayer distance of 2.2 nm, favoring K+ ion storage in aqueous electrolyte. In …
an increased interlayer distance of 2.2 nm, favoring K+ ion storage in aqueous electrolyte. In …
An Atomic View of Cation Diffusion Pathways from Single‐Crystal Topochemical Transformations
The diffusion pathways of Li‐ions as they traverse cathode structures in the course of
insertion reactions underpin many questions fundamental to the functionality of Li‐ion …
insertion reactions underpin many questions fundamental to the functionality of Li‐ion …