[PDF][PDF] Suppressing lithium dendrites within inorganic solid-state electrolytes

Q Lv, Y Jiang, B Wang, Y Chen, F Jin, B Wu… - Cell Reports Physical …, 2022 - cell.com
The Li metal anode possesses the high specific capacity and the minimum reduction
potential known as the renaissance of high-energy-density battery. However, the security …

NASICONs‐type solid‐state electrolytes: The history, physicochemical properties, and challenges

L Zhang, Y Liu, Y You, A Vinu… - Interdisciplinary Materials, 2023 - Wiley Online Library
Solid‐state electrolytes are critical for the development of next‐generation high‐energy and
high‐safety rechargeable batteries. Among all the candidates, sodium (Na) superionic …

[HTML][HTML] Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption

H Gao, X Ai, H Wang, W Li, P Wei, Y Cheng… - Nature …, 2022 - nature.com
Solid electrolytes hold the promise for enabling high-performance lithium (Li) metal
batteries, but suffer from Li-filament penetration issues. The mechanism of this rate …

Controlling dendrite propagation in solid-state batteries with engineered stress

CD Fincher, CE Athanasiou, C Gilgenbach, M Wang… - Joule, 2022 - cell.com
Metal-dendrite penetration is a mode of electrolyte failure that threatens the viability of metal-
anode-based solid-state batteries. Whether dendrites are driven by mechanical failure or …

Mechanical regulation of lithium intrusion probability in garnet solid electrolytes

G McConohy, X Xu, T Cui, E Barks, S Wang, E Kaeli… - Nature energy, 2023 - nature.com
Solid electrolytes in rechargeable lithium-metal batteries are susceptible to lithium-metal
short circuiting during plating, and the root cause is under debate. In this work, we …

Cryo‐EM Studies of Atomic‐Scale Structures of Interfaces in Garnet‐Type Electrolyte Based Solid‐State Batteries

Q Dai, J Yao, C Du, H Ye, Z Gao, J Zhao… - Advanced Functional …, 2022 - Wiley Online Library
High interfacial impedance is a major obstacle in the application of solid‐state Li metal
batteries (SSLMBs). Understanding the atomic‐scale structure of the interfaces in SSLMBs is …

Grain boundary engineering in Ta-doped garnet-type electrolyte for lithium dendrite suppression

Z Qin, Y Xie, X Meng, D Qian, D Mao… - … Applied Materials & …, 2022 - ACS Publications
Solid-state lithium batteries (SSLBs) based on Ta-doped Li6. 5La3Zr1. 5Ta0. 5O12 (LLZTO)
suffer from lithium dendrite growth, which hinders their practical application. Herein, first …

Transverse and longitudinal degradations in ceramic solid electrolytes

Y Dong, IW Chen, J Li - Chemistry of Materials, 2022 - ACS Publications
Ceramic solid electrolytes conducting primarily a specific ion but with minuscule electron
leakage are used in many electrochemical devices. Their degradation phenomena may be …

Solid-state batteries: The critical role of mechanics

S Kalnaus, NJ Dudney, AS Westover, E Herbert… - Science, 2023 - science.org
Solid-state batteries with lithium metal anodes have the potential for higher energy density,
longer lifetime, wider operating temperature, and increased safety. Although the bulk of the …

Tradeoff between the ion exchange-induced residual stress and ion transport in solid electrolytes

HD Jagad, SJ Harris, BW Sheldon, Y Qi - Chemistry of Materials, 2022 - ACS Publications
Rapid filament growth of lithium is limiting the commercialization of solid-state lithium metal
anode batteries. Recent work demonstrated that lithium filaments grow into pre-existing or …