High-energy and durable lithium metal batteries using garnet-type solid electrolytes with tailored lithium-metal compatibility

S Kim, JS Kim, L Miara, Y Wang, SK Jung… - Nature …, 2022 - nature.com
Lithium metal batteries using solid electrolytes are considered to be the next-generation
lithium batteries due to their enhanced energy density and safety. However, interfacial …

High-power hybrid solid-state lithium–metal batteries enabled by preferred directional lithium growth mechanism

S Kim, G Yoon, SK Jung, ST Park, JS Kim… - ACS Energy …, 2022 - ACS Publications
Solid electrolytes are revolutionizing the field of lithium–metal batteries; however, their
practical implementation has been impeded by the interfacial instability between lithium …

Dopant‐dependent stability of garnet solid electrolyte interfaces with lithium metal

Y Zhu, JG Connell, S Tepavcevic… - Advanced Energy …, 2019 - Wiley Online Library
Abstract Li7La3Zr2O12 (LLZO) garnet‐based materials doped with Al, Nb, or Ta to stabilize
the Li+‐conductive cubic phase are a particularly promising class of solid electrolytes for all …

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

K Fu, Y Gong, B Liu, Y Zhu, S Xu, Y Yao, W Luo… - Science …, 2017 - science.org
Solid-state batteries are a promising option toward high energy and power densities due to
the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from …

Degradation mechanism of all-solid-state Li-metal batteries studied by electrochemical impedance spectroscopy

EJ Cheng, Y Kushida, T Abe… - ACS applied materials & …, 2022 - ACS Publications
Solid-state Li-metal batteries have the potential to achieve both high safety and high energy
densities. Among various solid-state fast-ion conductors, the garnet-type Li7La3Zr2O12 …

In Situ Formed Shields Enabling Li2CO3-Free Solid Electrolytes: A New Route to Uncover the Intrinsic Lithiophilicity of Garnet Electrolytes for Dendrite-Free Li-Metal …

JF Wu, BW Pu, D Wang, SQ Shi, N Zhao… - … applied materials & …, 2018 - ACS Publications
Introduction of inorganic solid electrolytes is believed to be an ultimate strategy to dismiss
dendritic Li in high-energy Li-metal batteries (LMBs), and garnet-type Li7La3Zr2O12 (LLZO) …

Kinetic versus thermodynamic stability of LLZO in contact with lithium metal

JG Connell, T Fuchs, H Hartmann… - Chemistry of …, 2020 - ACS Publications
Li7La3Zr2O12 (LLZO) garnet-based oxides are a promising class of solid electrolytes used
as the separator in all-solid-state batteries (ASSBs). While LLZO is considered to have a …

Solvent-free and long-cycling garnet-based lithium-metal batteries

J Yu, W Zhai, C Zhang, C Wu, R Wei, S Chen… - ACS Energy …, 2023 - ACS Publications
Solid-state batteries using ceramic solid electrolytes promise to deliver enhanced energy
density and intrinsic safety. However, the challenge of integrating solid electrolytes with …

Garnet Si–Li7La3Zr2O12 electrolyte with a durable, low resistance interface layer for all-solid-state lithium metal batteries

X Ma, Y Xu, B Zhang, X Xue, C Wang, S He, J Lin… - Journal of Power …, 2020 - Elsevier
Abstract Solid garnet electrolyte Li 7 La 3 Zr 2 O 12 (LLZO) based Li metal batteries is a
promising candidate for the next generation high energy device due to the advantages of …

Building a better Li‐garnet solid electrolyte/metallic Li interface with antimony

R Dubey, J Sastre, C Cancellieri, F Okur… - Advanced Energy …, 2021 - Wiley Online Library
The deployment of Li‐garnet Li7La3Zr2O12 (LLZO) solid‐state electrolytes in solid‐state
batteries is severely hampered by their poor wettability with metallic Li. In this work, Sb is …