Optimizing Li+ transport in Li7La3Zr2O12 solid electrolytes

K Parascos, JL Watts, JA Alarco, Y Chen… - Ceramics International, 2023 - Elsevier
Abstract The Li+ conductivity of Li 7 La 3 Zr 2 O 12 (LLZO) solid electrolytes was optimized
by controlling the addition of the dopant (Al) into the crystal structure. A solution-based …

Synthesis of mixed ionic and electronic conducting garnet with doping of transition elements (Fe, Co, Ni)

X Cheng, J Huang, W Qiang, B Huang - Ceramics International, 2020 - Elsevier
Abstract Garnet structure electrolyte Li 7 La 3 Zr 2 O 12 (LLZO) exhibits high ionic
conductivity, high fracture toughness, and low strain during cycling. The mechanical stability …

Mechanistic understanding and strategies to design interfaces of solid electrolytes: insights gained from transmission electron microscopy

ZD Hood, M Chi - Journal of materials science, 2019 - Springer
Solid electrolytes (SEs) have gained increased attention for their promise to enable higher
volumetric energy density and enhanced safety required for future battery systems. SEs are …

Lattice‐Cell Orientation Disorder in Complex Spinel Oxides

Y Chen, Y Cheng, J Li, M Feygenson… - Advanced Energy …, 2017 - Wiley Online Library
Transition metal (TM) substitution has been widely applied to change complex oxides crystal
structures to create high energy density electrodes materials in high performance …

Recent developments in oxide-based ionic conductors: bulk materials, nanoionics, and their memory applications

T Wan, L Zhang, H Du, X Lin, B Qu, H Xu… - Critical Reviews in …, 2018 - Taylor & Francis
Oxide-based ionic conductors have attracted tremendous research interests due to their
wide applications in energy storage and conversion devices, such as photovoltaics, fuel …

Highly disordered amorphous Li-battery electrolytes

Y Zhu, ZD Hood, H Paik, PB Groszewicz, SP Emge… - Matter, 2024 - cell.com
Summary" Medium-entropy" highly disordered amorphous Li garnets, with≥ 4 unique local
bonding units (LBUs), hold promise for use as solid-state electrolytes in hybrid or all-solid …

Progress of lithium-ion transport mechanism in solid-state electrolytes

BK Zhang, LY Yang, SN Li… - Journal of …, 2021 - jelectrochem.xmu.edu.cn
Inorganic crystalline solid electrolytes exhibit exceptional room-temperature ionic
conductivities, giving them the potential to enable all-solid-state lithium (Li)-ion batteries …

Garnet materials for Li secondary batteries and methods of making and using garnet materials

T Holme, N Donnelly - US Patent 10,008,742, 2018 - Google Patents
Set forth herein are garnet material compositions, eg, lithium-stuffed garnets and lithium-
stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes …

Microwave assisted reactive sintering for Al doped Li7La3Zr2O12 lithium ion solid state electrolyte

D Gao, R Wu, P Chen, T Hong… - Materials Research …, 2020 - iopscience.iop.org
Abstract Li 6.28 Al 0.24 La 3 Zr 2 O 12 (Al-LLZO) solid electrolyte for Li-ion battery was
prepared by a microwave-assisted reactive sintering (MARS) method. When sintered by the …

Effects of Nonequilibrium Atomic Structure on Ionic Diffusivity in LLZO: A Classical and Machine Learning Molecular Dynamics Study

AC Grieder, K Kim, LF Wan, J Chapman… - The Journal of …, 2024 - ACS Publications
To improve the performance of electrochemical devices, it is essential to understand the
effects of nonequilibrium motifs in solids, such as grain boundaries, amorphous phases, and …